Professor Robert Mokaya
OBE FRS
School of Mathematical and Physical Sciences
Provost and Deputy Vice-Chancellor
Professor of Materials Chemistry
Full contact details
School of Mathematical and Physical Sciences
Firth Court
Western Bank
Sheffield
S10 2TN
- Profile
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Professor Robert Mokaya OBE FRS joined the University of Sheffield in 2024 as Provost and Deputy Vice-Chancellor from the University of Nottingham where he was Pro Vice-Chancellor for Global Engagement. Robert received his B.Sc. in Chemistry from the University of Nairobi in 1988 after which he spent a year working for Unilever in Kenya. He was awarded his Ph.D. from the University of Cambridge in 1992. In 1992 he was elected to a Research Fellowship at Trinity College, Cambridge and in 1996 was awarded an EPSRC Advanced Fellowship. He was appointed to a lectureship in Materials Chemistry at Nottingham in 2000, was promoted to Reader in Materials Chemistry in 2005, and to Professor of Materials Chemistry in 2008. He is a Royal Society Wolfson Research Merit Award holder (2017-2022). He was appointed OBE in 2022 for services to the Chemical Sciences and was elected Fellow of the Royal Society in 2023. He is President-Elect of the Royal Society of Chemistry (2024 – 2026) and will be President for the period 2026 to 2028.
- Research interests
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The design, synthesis and characterisation of novel porous materials and the study of their structure- property relations is the focus of our research interests. The materials currently under investigation are those which may find use as solid state catalysts, adsorbents (especially for sustainable energy storage applications), molecular sieves and as hosts in the preparation of advanced composite materials. Of particular interest are templated porous solids and materials prepared via valorisation routes that are simple and sustainable. Examples are (i) zeolite templated carbons that replicate the structure of microporous zeolites, (ii) mesoporous molecular sieves (MMS) prepared via the 'Liquid Crystal Templating' (LCT) mechanism in which supramolecular assemblies of surfactant serve as components of the template for the formation of solid inorganic frameworks, and (iii) porous carbons generated via activation and carbonisation routes that encompass valorisation.
- Publications
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Journal articles
- Capacity building in porous materials research for sustainable energy applications. Interface Focus, 14(4).
- Modulating the porosity of N-doped carbon materials for enhanced CO2 capture and methane uptake. Journal of Materials Chemistry A, 12(32), 21025-21040. View this article in WRRO
- Electrochemical Sensor for Ascorbic Acid, Acetaminophen and Nitrite Based on Organoclay/Zr‐MOF Film Modified Glassy Carbon Electrode. ChemistrySelect, 7(40).
- Calcium coordination compounds of anionic forms of hydrogen dipicolinate and quinolinate: synthesis, characterization, crystal structures and DFT studies. Structural Chemistry, 33(4), 1257-1269.
- A Co-Crystallised Cobalt(II) Cluster of Pyridinedicarboxylic Acid (PDC) as a Luminescent Material for Selective Sensing of Methanol. Journal of Fluorescence, 31(4), 1177-1190.
- Co-pelletization of a zirconium-based metal-organic framework (UiO-66) with polymer nanofibers for improved useable capacity in hydrogen storage. International Journal of Hydrogen Energy, 46(12), 8607-8620.
- Synthesis, characterization and density functional theory of copper(II) complex and cobalt(II) coordination polymer for detection of nitroaromatic explosives. Inorganica Chimica Acta, 515, 120048-120048.
- Experimental Demonstration of Dynamic Temperature-Dependent Behavior of UiO-66 Metal–Organic Framework: Compaction of Hydroxylated and Dehydroxylated Forms of UiO-66 for High-Pressure Hydrogen Storage. ACS Applied Materials & Interfaces, 12(22), 24883-24894.
- Catalytic Upgrading of Pyrolytic Oil via In-situ Hydrodeoxygenation. Waste and Biomass Valorization, 11(6), 2935-2947.
- The effects of metakaolinization and fused-metakaolinization on zeolites synthesized from quartz rich natural clays. Microporous and Mesoporous Materials, 290, 109668-109668.
- Pore Characteristics for Efficient CO2 Storage in Hydrated Carbons. ACS Applied Materials & Interfaces, 11(47), 44390-44398.
- New perspectives on supercritical methane adsorption in shales and associated thermodynamics. Journal of Industrial and Engineering Chemistry, 78, 186-197.
- Integrated biomass thermochemical conversion for clean energy production: Process design and economic analysis. Journal of Environmental Chemical Engineering, 7(3), 103093-103093.
- Biofuel and valuable products recovery from Napier grass pre-processing: Process design and economic analysis. Journal of Environmental Chemical Engineering, 7(2), 102962-102962.
- Valorisation of adzuki bean waste to biofuel precursors via pyrolysis: kinetics, product distribution and characterisation. Biomass Conversion and Biorefinery, 8(3), 699-710.
- Optimization of the Pore Structure of Biomass-Based Carbons in Relation to Their Use for CO2 Capture under Low- and High-Pressure Regimes. ACS Applied Materials & Interfaces, 10(2), 1623-1633.
- Highly Porous Renewable Carbons for Enhanced Storage of Energy-Related Gases (H2 and CO2) at High Pressures. ACS Sustainable Chemistry & Engineering, 4(9), 4710-4716.
- Is N-Doping in Porous Carbons Beneficial for CO2 Storage? Experimental Demonstration of the Relative Effects of Pore Size and N-Doping. Chemistry of Materials, 28(3), 994-1001.
- Compactivation: A mechanochemical approach to carbons with superior porosity and exceptional performance for hydrogen and CO2 storage. Nano Energy, 16, 173-185.
- Generalized Mechanochemical Synthesis of Biomass‐Derived Sustainable Carbons for High Performance CO2 Storage. Advanced Energy Materials, 5(22).
- A hygrothermal modelling approach to water vapour sorption isotherm design for mesoporous humidity buffers. Microporous and Mesoporous Materials, 211, 113-123.
- Valorization of Lignin Waste: Carbons from Hydrothermal Carbonization of Renewable Lignin as Superior Sorbents for CO2 and Hydrogen Storage. ACS Sustainable Chemistry & Engineering, 3(7), 1658-1667.
- A CVD route for the preparation of templated and activated carbons for gas storage applications using zeolitic imidazolate frameworks (ZIFs) as template. Microporous and Mesoporous Materials, 195, 258-265.
- Porosity modulation of activated ZIF-templated carbons via compaction for hydrogen and CO2 storage applications. Journal of Materials Chemistry A, 2(28), 10960-10960.
- Tuning the acidic and textural properties of ordered mesoporous silicas for their application as catalysts in the etherification of glycerol with isobutene. Catalysis Today, 227, 171-178.
- Steam Stable Mesoporous Silica MCM-41 Stabilized by Trace Amounts of Al. ACS Applied Materials & Interfaces, 6(3), 1902-1908.
- High surface area metal salt templated carbon aerogels via a simple subcritical drying route: preparation and CO2 uptake properties. RSC Advances, 3(39), 17677-17677.
- Microporous activated carbon aerogels via a simple subcritical drying route for CO2 capture and hydrogen storage. Microporous and Mesoporous Materials, 179, 151-156.
- Supercritical CO2 Mediated Incorporation of Pd onto Templated Carbons: A Route to Optimizing the Pd Particle Size and Hydrogen Uptake Density. ACS Applied Materials & Interfaces, 5(12), 5639-5647.
- Preparation of ultrahigh surface area porous carbons templated using zeolite 13X for enhanced hydrogen storage. Progress in Natural Science: Materials International, 23(3), 308-316.
- Hydrogen Storage in High Surface Area Carbons with Identical Surface Areas but Different Pore Sizes: Direct Demonstration of the Effects of Pore Size. The Journal of Physical Chemistry C, 116(49), 25734-25740.
- Hidden crystalline components in mesoporous silicate. Journal of Materials Chemistry, 22(43), 23141-23141.
- On the Shelf Life and Aging Stability of Mesoporous Silica: Insights on Thermodynamically Stable MCM-41 Structure from Assessment of 12-Year-Old Samples. Chemistry of Materials, 24(22), 4450-4458.
- High temperature synthesis of exceptionally stable pure silica MCM-41 and stabilisation of calcined mesoporous silicas via refluxing in water. Journal of Materials Chemistry, 22(36), 18872-18872.
- Polypyrrole‐Derived Activated Carbons for High‐Performance Electrical Double‐Layer Capacitors with Ionic Liquid Electrolyte. Advanced Functional Materials, 22(4), 827-834.
- Preparation and hydrogen storage capacity of highly porous activated carbon materials derived from polythiophene. International Journal of Hydrogen Energy, 36(24), 15658-15663.
- Carbon nanotube/titanium dioxide (CNT/TiO2) core–shell nanocomposites with tailored shell thickness, CNT content and photocatalytic/photoelectrocatalytic properties. Applied Catalysis B: Environmental, 110, 50-57.
- The effect of Al content of zeolite template on the properties and hydrogen storage capacity of zeolite templated carbons. Microporous and Mesoporous Materials, 144(1-3), 140-147.
- Ultrahigh surface area polypyrrole-based carbons with superior performance for hydrogen storage. Energy & Environmental Science, 4(8), 2930-2930.
- Super-micropore/small mesopore composite pillared silicate and aluminosilicate materials from crystalline layered silicate Na-RUB-18. Microporous and Mesoporous Materials, 143(1), 104-114.
- Characterisation and hydrogen storage of Pt-doped carbons templated by Pt-exchanged zeolite Y. Microporous and Mesoporous Materials, 142(2-3), 716-724.
- Superior CO2 Adsorption Capacity on N‐doped, High‐Surface‐Area, Microporous Carbons Templated from Zeolite. Advanced Energy Materials, 1(4), 678-683.
- Hydrothermal Carbonization of Abundant Renewable Natural Organic Chemicals for High‐Performance Supercapacitor Electrodes. Advanced Energy Materials, 1(3), 356-361.
- Mesoporous Aluminosilicates from a Zeolite BEA Recipe. Chemistry of Materials, 23(9), 2491-2498.
- High density hydrogen storage in superactivated carbons from hydrothermally carbonized renewable organic materials. Energy & Environmental Science, 4(4), 1400-1400.
- Hydrothermal Carbonization of Abundant Renewable Natural Organic Chemicals for High-Performance Supercapacitor Electrodes. Advanced Energy Materials, n/a-n/a.
- A simplified synthesis of N-doped zeolite-templated carbons, the control of the level of zeolite-like ordering and its effect on hydrogen storage properties. Carbon, 49(3), 844-853.
- CVD Nanocasting Routes to Zeolite‐Templated Carbons for Hydrogen Storage. Chemical Vapor Deposition, 16(10-12), 322-328.
- Evolution of optimal porosity for improved hydrogen storage in templated zeolite-like carbons. Energy & Environmental Science, 3(11), 1773-1773.
- Enhancement of Hydrogen Storage Capacity of Zeolite-Templated Carbons by Chemical Activation. The Journal of Physical Chemistry C, 114(25), 11314-11319.
- Templated nanoscale porous carbons. Nanoscale, 2(5), 639-639.
- Hydrogen Storage in High Surface Area Carbons: Experimental Demonstration of the Effects of Nitrogen Doping. Journal of the American Chemical Society, 131(45), 16493-16499.
- Nanocasting of High Surface Area Mesoporous Ga2O3 and GaN Semiconductor Materials. Chemistry of Materials, 21(17), 4080-4086.
- Electrical Double-Layer Capacitance of Zeolite-Templated Carbon in Organic Electrolyte. Journal of The Electrochemical Society, 156(1), A1-A1.
- Aligned Bundles of Carbon Nanotubes Are Easily Grown on As-Synthesized Mesoporous Silicate Substrates. The Journal of Physical Chemistry C, 112(39), 15157-15162.
- Probing the effect of the carbonisation process on the textural properties and morphology of mesoporous carbons. Microporous and Mesoporous Materials, 113(1-3), 378-384.
- Crystalline mesoporous silicates from layered precursors. Journal of Materials Chemistry, 18(12), 1383-1383.
- Synthesis and High Hydrogen Storage Capacity of Zeolite-Like Carbons Nanocast Using As-Synthesized Zeolite Templates. The Journal of Physical Chemistry C, 112(7), 2764-2769.
- Mesoporous MCM-48 Aluminosilica Oxynitrides: Synthesis and Characterization of Bifunctional Solid Acid−Base Materials. The Journal of Physical Chemistry C, 112(5), 1455-1462.
- Novel mesoporous silicoaluminophosphates as highly active and selective materials in the Beckmann rearrangement of cyclohexanone and cyclododecanone oximes. Journal of Catalysis, 252(1), 1-10.
- Self-Assembled Ultralarge Millimeter-Sized Graphitic Carbon Rods Grown on Mesoporous Silica Substrate. Chemistry of Materials, 19(25), 6317-6322.
- Layered double hydroxides as templates for nanocasting porous N-doped graphitic carbons via chemical vapour deposition. Microporous and Mesoporous Materials, 106(1-3), 147-154.
- Novel one step hydrothermal synthesis of TiO2/WO3 nanocomposites with enhanced photocatalytic activity. Chemical Communications(45), 4749-4749.
- Ordered Mesoporous Carbon Monoliths: CVD Nanocasting and Hydrogen Storage Properties. The Journal of Physical Chemistry C, 111(27), 10035-10039.
- Enhanced Hydrogen Storage Capacity of High Surface Area Zeolite-like Carbon Materials. Journal of the American Chemical Society, 129(6), 1673-1679.
- Oxidation of cyclooctane over metalloporphyrin-exchanged Al,Si-mesoporous molecular sieves of HMS (MMS) type. Applied Catalysis A: General, 313(1), 106-111.
- Molecularly ordered layered aluminosilicate-surfactant mesophases and their conversion to hydrothermally stable mesoporous aluminosilicates. Microporous and Mesoporous Materials, 94(1-3), 295-303.
- Preparation and Hydrogen Storage Properties of Zeolite-Templated Carbon Materials Nanocast via Chemical Vapor Deposition: Effect of the Zeolite Template and Nitrogen Doping. The Journal of Physical Chemistry B, 110(37), 18424-18431.
- Periodic mesoporous organosilica mesophases are versatile precursors for the direct preparation of mesoporous silica/carbon composites, carbon and silicon carbide materials. Journal of Materials Chemistry, 16(33), 3417-3417.
- A Porous Framework Polymer Based on a Zinc(II) 4,4‘-Bipyridine-2,6,2‘,6‘-tetracarboxylate: Synthesis, Structure, and “Zeolite-Like” Behaviors. Journal of the American Chemical Society, 128(33), 10745-10753.
- Synthesis of mesoporous silica hollow spheres in supercritical CO2/water systems. Journal of Materials Chemistry, 16(18), 1751-1751.
- Oxidation of cyclooctane over Mn(TMPyP) porphyrin-exchanged Al,Si-mesoporous molecular sieves of MCM-41 and SBA-15 type. Catalysis Today, 114(2-3), 287-292.
- Crystalline-like Molecularly Ordered Mesoporous Aluminosilicates Derived from Aluminosilica−Surfactant Mesophases via Benign Template Removal. The Journal of Physical Chemistry B, 110(18), 9122-9131.
- Synthesis and characterization of novel mesoporous aluminosilicate MCM-41 containing aluminophosphate building units. Chemical Communications(17), 1839-1839.
- Simultaneous Control of Morphology and Porosity in Nanoporous Carbon: Graphitic Mesoporous Carbon Nanorods and Nanotubules with Tunable Pore Size.. ChemInform, 37(12).
- Molecularly Ordered Ethylene-Bridged Periodic Mesoporous Organosilica Spheres with Tunable Micrometer Sizes. Chemistry of Materials, 18(5), 1141-1148.
- Surfactant Mediated Control of Pore Size and Morphology for Molecularly Ordered Ethylene-Bridged Periodic Mesoporous Organosilica. The Journal of Physical Chemistry B, 110(9), 3889-3894.
- Simultaneous Control of Morphology and Porosity in Nanoporous Carbon: Graphitic Mesoporous Carbon Nanorods and Nanotubules with Tunable Pore Size. Chemistry of Materials, 18(1), 140-148.
- Hollow shells of high surface area graphitic N-doped carbon composites nanocast using zeolite templates. Microporous and Mesoporous Materials, 86(1-3), 69-80.
- High surface area ethylene-bridged mesoporous and supermicroporous organosilica spheres. Microporous and Mesoporous Materials, 86(1-3), 231-242.
- Reply: Mesoporous Zeolite ZSM‐5 Nanocast from Mesoporous Carbon Templates. Advanced Materials, 17(23), 2791-2792.
- Comment: Questions Concerning the Nitrogen Adsorption Data Analysis for Formation of Supermicropores in ZSM‐5 Zeolites. Advanced Materials, 17(23), 2789-2791.
- Hollow spheres of crystalline porous metal oxides: A generalized synthesis route via nanocasting with mesoporous carbon hollow shells. Journal of Materials Chemistry, 15(30), 3126-3126.
- Aligned N-Doped Carbon Nanotube Bundles Prepared via CVD Using Zeolite Substrates. Chemistry of Materials, 17(17), 4502-4508.
- Generalized and Facile Synthesis Approach to N-Doped Highly Graphitic Mesoporous Carbon Materials. Chemistry of Materials, 17(6), 1553-1560.
- Photophysical Properties of [60]Fullerenes and Phthalocyanines Embedded in Ordered Mesoporous Silica Films Annealed at Various Temperatures. The Journal of Physical Chemistry B, 109(11), 5079-5084.
- Bifunctional Hybrid Mesoporous Organoaluminosilicates with Molecularly Ordered Ethylene Groups. Journal of the American Chemical Society, 127(2), 790-798.
- Synthesis of siliceous hollow spheres with large mesopore wall structure by supercritical CO2-in-water interface templating. Chemical Communications(2), 210-210.
- Mesostructured Hollow Spheres of Graphitic N-Doped Carbon Nanocast from Spherical Mesoporous Silica. The Journal of Physical Chemistry B, 108(50), 19293-19298.
- Are mesoporous silicas and aluminosilicas assembled from zeolite seeds inherently hydrothermally stable? Comparative evaluation of MCM-48 materials assembled from zeolite seeds. Journal of Materials Chemistry, 14(23), 3427-3427.
- Synthesis of Ordered Mesoporous Carbon and Nitrogen‐Doped Carbon Materials with Graphitic Pore Walls via a Simple Chemical Vapor Deposition Method. Advanced Materials, 16(17), 1553-1558.
- Enhanced hydrothermal stability of Al-grafted MCM-48 prepared via various alumination routes. Microporous and Mesoporous Materials, 74(1-3), 179-188.
- High Surface Area Silicon Carbide Whiskers and Nanotubes Nanocast Using Mesoporous Silica. Chemistry of Materials, 16(20), 3877-3884.
- Ordered mesoporous MCM-41 silicon oxynitride solid base materials with high nitrogen content: synthesis, characterisation and catalytic evaluation. Journal of Materials Chemistry, 14(16), 2507-2507.
- Formation of Molecularly Ordered Layered Mesoporous Silica via Phase Transformation of Silicate−Surfactant Composites. The Journal of Physical Chemistry B, 108(31), 11361-11367.
- Ordered Mesoporous Carbon Hollow Spheres Nanocast Using Mesoporous Silica via Chemical Vapor Deposition. Advanced Materials, 16(11), 886-891.
- Zeolite ZSM‐5 with Unique Supermicropores Synthesized Using Mesoporous Carbon as a Template. Advanced Materials, 16(8), 727-732.
- Supercritical fluids: A route to palladium-aerogel nanocomposites. Journal of Materials Chemistry, 14(7), 1212-1212.
- Aluminosilicate MCM-48 materials with enhanced stability via simple post-synthesis treatment in water. Microporous and Mesoporous Materials, 68(1-3), 1-10.
- On the synthesis and characterization of ZSM-5/MCM-48 aluminosilicate composite materials. Journal of Materials Chemistry, 14(5), 863-863.
- Stability of Pillared Clays: Effect of Compaction on the Physicochemical Properties of Al-Pillared Clays. Chemistry of Materials, 16(2), 263-269.
- A study of the behaviour of mesoporous silicas in OH/CTABr/H2O systems: phase dependent stabilisation, dissolution or semi-pseudomorphic transformation. Journal of Materials Chemistry, 13(12), 3112-3112.
- On the Hydrothermal Stability of Mesoporous Aluminosilicate MCM-48 Materials. The Journal of Physical Chemistry B, 107(29), 6954-6960.
- Highly Ordered Mesoporous Silicon Oxynitride Materials as Base Catalysts. Angewandte Chemie International Edition, 42(23), 2639-2644.
- Highly Ordered Mesoporous Silicon Oxynitride Materials as Base Catalysts. Angewandte Chemie, 115(23), 2743-2748.
- Synthesis of transparent and ordered mesoporous silica monolithic films embedded with monomeric zinc phthalocyanine dye. Chemical Communications(7), 860-861.
- Facile and high yield synthesis of mesostructured MCM-48 silica crystals. Journal of Materials Chemistry, 13(4), 657-659.
- Transparent thin films and monoliths synthesized from fullerene doped mesoporous silica: evidence for embedded monodispersed C60Electronic supplementary information (ESI) available: diffuse reflectance spectra of C60 embedded in mesoporous molecular sieve films. See http://www.rsc.org/suppdata/cc/b2/b208615h/. Chemical Communications(1), 92-93.
- New Insights into the Spatial Distribution of Aluminium in Various Mesoporous Aluminosilicates. ChemPhysChem, 3(10), 892-896.
- Supercritical Fluid-Mediated Alumination of Mesoporous Silica and Its Beneficial Effect on Hydrothermal Stability. Journal of the American Chemical Society, 124(36), 10636-10637.
- On the extended recrystallisation of mesoporous silica: characterisation of restructured pure silica MCM-41. Journal of Materials Chemistry, 12(10), 3027-3033.
- Alumination Pathways to Mesoporous Aluminosilicates with High-Temperature Hydrothermal Stability. ChemPhysChem, 3(4), 360-363.
- . Chemical Communications(20), 2100-2101.
- Oxidation of cyclohexene over Mn(TMPyP) porphyrin-exchanged Al,Si-mesoporous molecular sieves. Applied Catalysis A: General, 218(1-2), 211-217.
- Observation of some pore wall ordering in mesoporous silica. Chemical Communications(12), 1092-1093.
- Super-microporous aluminosilicate catalysts via primary amine templating. Chemical Communications(11), 1016-1017.
- Hydrothermally-induced morphological transformation of mesoporous MCM-41 silica. Microporous and Mesoporous Materials, 44-45, 119-127.
- Hydrothermally stable restructured mesoporous silica. Chemical Communications(10), 933-934.
- Influence of pore wall thickness on the steam stability of Al-grafted MCM-41. Chemical Communications(7), 633-634.
- ChemInform Abstract: Improving the Stability of Mesoporous MCM‐41 Silica via Thicker More Highly Condensed Pore Walls.. ChemInform, 31(8).
- Synthesis of Mesoporous Aluminosilicates with Enhanced Stability and Ion-Exchange Capacity via a Secondary Crystallization Route. Advanced Materials, 12(22), 1681-1685.
- Insertion of extra-framework Al into the framework of mesoporous MCM-41 aluminosilicates. Chemical Communications(19), 1891-1892.
- Template-directed stepwise post-synthesis alumination of MCM-41 mesoporous silica. Chemical Communications(16), 1541-1542.
- Al Content Dependent Hydrothermal Stability of Directly Synthesized Aluminosilicate MCM-41. The Journal of Physical Chemistry B, 104(34), 8279-8286.
- Alxn+-grafted MCM-41 Catalysts: Probing the Influence of Temperature on the Alumination Process. Journal of Catalysis, 193(1), 103-107.
- Restructuring of mesoporous silica: high quality large crystal MCM‐41 via a seeded recrystallisation route. Journal of Materials Chemistry, 10(5), 1139-1145.
- ChemInform Abstract: Grafting of Al onto Purely Siliceous Mesoporous Molecular Sieves.. ChemInform, 30(12).
- Improving the Stability of Mesoporous MCM-41 Silica via Thicker More Highly Condensed Pore Walls. The Journal of Physical Chemistry B, 103(46), 10204-10208.
- The “silica garden’' as a Brønsted acid catalyst. Physical Chemistry Chemical Physics, 1(19), 4669-4672.
- Ultrastabile mesoporöse Alumosilicate durch Pfropfsynthesen. Angewandte Chemie, 111(19), 3079-3083.
- Ultrastable Mesoporous Aluminosilicates by Grafting Routes. Angewandte Chemie International Edition, 38(19), 2930-2934.
- A method for the synthesis of high quality large crystal MCM-41. Chemical Communications(1), 51-52.
- The Effect of Particle Size on Aluminosilicate MCM-41 Catalysts Prepared via Grafting Routes. Journal of Catalysis, 186(2), 470-477.
- Efficient post-synthesis alumination of MCM-41 using aluminium chlorohydrate containing Al polycations. Journal of Materials Chemistry, 9(2), 555-561.
- Grafting of Al onto purely siliceous mesoporous molecular sieves. Physical Chemistry Chemical Physics, 1(1), 207-213.
- ChemInform Abstract: Aluminosilicate Mesoporous Molecular Sieves with Enhanced Stability Obtained by Reacting MCM‐41 with Aluminum Chlorohydrate.. ChemInform, 29(45).
- Aluminosilicate mesoporous molecular sieves with enhanced stability obtained by reacting MCM-41 with aluminium chlorohydrate. Chemical Communications(17), 1839-1840.
- The influence of template extraction on the properties of primary amine templated aluminosilicate mesoporous molecular sieves. Journal of Materials Chemistry, 8(12), 2819-2826.
- ChemInform Abstract: Synthesis, Characterization, and Formation Mechanism of the Mesoporous Molecular Sieve MCM‐41. ChemInform, 28(17).
- . Catalysis Letters, 49(1/2), 87-94.
- Physicochemical Characterisation and Catalytic Activity of Primary Amine Templated Aluminosilicate Mesoporous Catalysts. Journal of Catalysis, 172(1), 211-221.
- Post-synthesis grafting of Al onto MCM-41. Chemical Communications(22), 2185-2186.
- Acidity and catalytic activity of the mesoporous aluminosilicate molecular sieve MCM-41. Catalysis Letters, 37(1-2), 113-120.
- Synthesis of acidic aluminosilicate mesoporous molecular sieves using primary amines. Chemical Communications(8), 981-981.
- Acidity and catalytic activity of aluminosilicate mesoporous molecular sieves prepared using primary amines. Chemical Communications(8), 983-983.
- ChemInform Abstract: Pillared Clays and Pillared Acid‐Activated Clays: A Comparative Study of Physical, Acidic, and Catalytic Properties.. ChemInform, 26(44).
- Pillared Clays and Pillared Acid-Activated Clays: A Comparative-Study of Physical, Acidic, and Catalytic Properties. Journal of Catalysis, 153(1), 76-85.
- The microstructure of alumina pillared acid-activated clays. Journal of Porous Materials, 1(1), 97-110.
- Pillared acid-activated clay catalysts. Journal of the Chemical Society, Chemical Communications(8), 929-929.
- The Mechanism of Chlorophyll Adsorption on Acid-Activated Clays. Journal of Solid State Chemistry, 111(1), 157-163.
- Chlorophyll adsorption by alumina‐pillared acid‐activated clays. Journal of the American Oil Chemists' Society, 70(3), 241-244.
- Preparation of alumina-pillared acid-activated clays and their use as chlorophyll adsorbents. Journal of Materials Chemistry, 3(4), 381-381.
- Synthesis And Characterization Of Pillared Acid-Activated Montmorillonites. MRS Proceedings, 233.
- Ultra-high surface area ionic-liquid-derived carbons that meet both gravimetric and volumetric methane storage targets. Energy & Environmental Science, 17(9), 3060-3076.
- Porous carbon composites as clean energy materials with extraordinary methane storage capacity. Energy & Environmental Science, 17(14), 5024-5038.
- Synthesis and Characterization of Doped Magnesium Hydroxide for Medium Heat Storage Application. Materials, 16(18), 6296-6296.
- Solvothermal synthesis of organoclay/Cu-MOF composite and its application in film modified GCE for simultaneous electrochemical detection of deoxyepinephrine, acetaminophen and tyrosine. RSC Advances, 13(30), 20816-20829.
- Hydrothermal synthesis of zeolites using silica extracted from tropical volcanic ash. Materials Advances, 4(10), 2292-2300.
- Direct synthesis of organic salt-derived porous carbons for enhanced CO2 and methane storage. Journal of Materials Chemistry A, 11(13), 6952-6965.
- A simple, sustainable route to flexible microporous carbon cloth for energy storage applications. Materials Advances, 4(16), 3559-3571.
- Optimization of biodiesel synthesis from Jatropha curcas oil using kaolin derived zeolite Na–X as a catalyst. RSC Advances, 12(35), 22792-22805.
- Rational synthesis of microporous carbons for enhanced post-combustion CO2 capture via non-hydroxide activation of air carbonised biomass. RSC Advances, 12(31), 20080-20087.
- Modulating the porosity of carbons for improved adsorption of hydrogen, carbon dioxide, and methane: a review. Materials Advances, 3(4), 1905-1930.
- Direct and mild non-hydroxide activation of biomass to carbons with enhanced CO2 storage capacity. Energy Advances, 1(4), 216-224.
- Confirmation of pore formation mechanisms in biochars and activated carbons by dual isotherm analysis. Materials Advances, 3(9), 3961-3971.
- Modulating the porosity of activated carbons via pre-mixed precursors for simultaneously enhanced gravimetric and volumetric methane uptake. Journal of Materials Chemistry A, 10(26), 13744-13757.
- Generalised predictability in the synthesis of biocarbons as clean energy materials: targeted high performance CO2 and CH4 storage. Energy & Environmental Science, 15(11), 4710-4724.
- Brute force determination of the optimum pore sizes for CO2 uptake in turbostratic carbons. Energy Advances, 1(12), 1009-1020.
- Author Correction: Oxygen-rich microporous carbons with exceptional hydrogen storage capacity. Nature Communications, 12(1).
- Potential of Bioenergy in Rural Ghana. Sustainability, 13(1), 381-381.
- Effect of kaolin pre-treatment method and NaOH levels on the structure and properties of kaolin-derived faujasite zeolites. Materials Advances, 2(18), 5997-6010.
- Correction: Exceptional gravimetric and volumetric hydrogen storage for densified zeolite templated carbons with high mechanical stability. Energy & Environmental Science, 14(3), 1618-1618.
- Simultaneous quantification of acetaminophen and tryptophan using a composite graphene foam/Zr-MOF film modified electrode. New Journal of Chemistry, 44(30), 13108-13117.
- Predictable and targeted activation of biomass to carbons with high surface area density and enhanced methane storage capacity. Energy & Environmental Science, 13(9), 2967-2978.
- Porous carbons from sustainable sources and mild activation for targeted high-performance CO2 capture and storage. Materials Advances, 1(9), 3267-3280.
- Pre-mixed precursors for modulating the porosity of carbons for enhanced hydrogen storage: towards predicting the activation behaviour of carbonaceous matter. Journal of Materials Chemistry A, 7(29), 17466-17479.
- Valorization of lignin waste: high electrochemical capacitance of lignin-derived carbons in aqueous and ionic liquid electrolytes. Journal of Materials Chemistry A, 6(38), 18701-18711.
- Compaction of a zirconium metal–organic framework (UiO-66) for high density hydrogen storage applications. Journal of Materials Chemistry A, 6(46), 23569-23577.
- A simple flash carbonization route for conversion of biomass to porous carbons with high CO2 storage capacity. Journal of Materials Chemistry A, 6(26), 12393-12403.
- Oxygen-rich microporous carbons with exceptional hydrogen storage capacity. Nature Communications, 8(1).
- Biomass to porous carbon in one step: directly activated biomass for high performance CO2 storage. Journal of Materials Chemistry A, 5(24), 12330-12339.
- Cigarette butt-derived carbons have ultra-high surface area and unprecedented hydrogen storage capacity. Energy & Environmental Science, 10(12), 2552-2562.
- Ultra-high surface area mesoporous carbons for colossal pre combustion CO2 capture and storage as materials for hydrogen purification. Sustainable Energy & Fuels, 1(6), 1414-1424.
- Bridging the performance gap between electric double-layer capacitors and batteries with high-energy/high-power carbon nanotube-based electrodes. Journal of Materials Chemistry A, 4(38), 14586-14594.
- Biomass-derived activated carbon with simultaneously enhanced CO2 uptake for both pre and post combustion capture applications. Journal of Materials Chemistry A, 4(1), 280-289.
- Templating of carbon in zeolites under pressure: synthesis of pelletized zeolite templated carbons with improved porosity and packing density for superior gas (CO2 and H2) uptake properties. Journal of Materials Chemistry A, 4(37), 14254-14266.
- High yield and high packing density porous carbon for unprecedented CO2 capture from the first attempt at activation of air-carbonized biomass. Journal of Materials Chemistry A, 4(34), 13324-13335.
- Low temperature synthesized carbon nanotube superstructures with superior CO2and hydrogen storage capacity. Journal of Materials Chemistry A, 3(9), 5148-5161.
- Hygrothermal simulation-informed design of mesoporous desiccants for optimised energy efficiency of mixed mode air conditioning systems. Journal of Materials Chemistry A, 3(33), 17290-17303.
- Strongly acidic mesoporous aluminosilicates prepared via hydrothermal restructuring of a crystalline layered silicate. Journal of Materials Chemistry A, 3(15), 7799-7809.
- A family of microporous carbons prepared via a simple metal salt carbonization route with high selectivity for exceptional gravimetric and volumetric post-combustion CO2capture. Journal of Materials Chemistry A, 2(35), 14696-14696.
- Exceptional gravimetric and volumetric hydrogen storage for densified zeolite templated carbons with high mechanical stability. Energy & Environmental Science, 7(1), 427-434.
- Preparation and hydrogen storage capacity of templated and activated carbons nanocast from commercially available zeolitic imidazolate framework. J. Mater. Chem., 22(1), 146-152.
- Activation of carbide-derived carbons: a route to materials with enhanced gas and energy storage properties. J. Mater. Chem., 21(13), 4727-4732.
- One step room temperature synthesis of ordered mesoporous silicaSBA-15 mediated by cellulose nanoparticles. J. Mater. Chem., 20(2), 320-325.
- Superactivated carbide-derived carbons with high hydrogenstorage capacity. Energy Environ. Sci., 3(2), 223-227.
- Mesoporous boron nitride and boron-nitride-carbon materials from mesoporous silica templates. J. Mater. Chem., 18(2), 235-241.
- To stir or not to stir: formation of hierarchical superstructures of molecularly ordered ethylene-bridged periodic mesoporous organosilicas. J. Mater. Chem., 16(4), 395-400.
Chapters
- Templated Porous Carbon Materials: Recent Developments (pp. 217-264). Wiley
- Synthesis of mesoporous aluminosilicates via recrystallisation of pure silica MCM-41: A stepwise post-synthesis alumination route, Studies in Surface Science and Catalysis (pp. 123-126). Elsevier
- Preparation of versatile silica/carbon nanocomposites via carbonization of ethyl-bridged periodic mesoporous organosilica, Studies in Surface Science and Catalysis (pp. 393-396). Elsevier
- Facile low temperature synthesis of primary amine templated super-microporous aluminosilicates, Studies in Surface Science and Catalysis (pp. 519-522). Elsevier
- SURFACE ALUMINATION OF MESOPOROUS SILICATES, Series on Chemical Engineering (pp. 427-463). PUBLISHED BY IMPERIAL COLLEGE PRESS AND DISTRIBUTED BY WORLD SCIENTIFIC PUBLISHING CO.
- Mesoporous Materials, Synthesis and Properties, Encyclopedia of Physical Science and Technology (pp. 369-381). Elsevier
- ION EXCHANGE | Novel Layered Materials: Non-Phosphates, Encyclopedia of Separation Science (pp. 1610-1617). Elsevier
- Pillared Acid-Activated Clays : Synthesis, Characterisation and Application to Chlorophyll Adsorption, Multifunctional Mesoporous Inorganic Solids (pp. 425-432). Springer Netherlands
Conference proceedings papers
- Microporosity in Mesoporous SBA-15 Supports: A Factor Influencing the Catalytic Performance of Immobilized Metalloporphyrin. Topics in Catalysis, Vol. 52(8) (pp 1098-1104)
- POROUS CARBON MATERIALS VIA CHEMICAL VAPOUR DEPOSITION USING AS-SYNTHESISED ZEOLITES AS TEMPLATE: SYNTHESIS AND HYDROGEN STORAGE PROPERTIES. Nanoporous Materials (pp 283-292)
- EFFECT OF CARBONISATION HEATING RAMP RATE ON THE PROPERTIES OF ORDERED MESOPOROUS CARBONS. Nanoporous Materials (pp 293-302)
- Synthesis of hollow spherical mesoporous N-doped carbon materials with graphitic framework (pp 565-572)
- Mesostructured aluminosilica oxynitrides: solid acid-base materials prepared via post-synthesis grafting routes (pp 125-132)
- Porous N-doped carbon with various hollow-cored morphologies nanocast using zeolite templates via chemical vapour deposition (pp 573-580)
- Influence of alumination pathway on the steam stability of Al-grafted MCM-41 (pp 435-438)
- Synthesis and characterisation of super-microporous aluminosilicates prepared via primary amine templating (pp 141-150)
- Direct Synthesis of Acidic Aluminosilicate Mesoporous Molecular Sieves. MRS Proceedings, Vol. 431
- Energy storage applications of activated carbons: supercapacitors and hydrogen storage. Energy Environ. Sci., Vol. 7(4) (pp 1250-1280)
Other
- A cleaner way to nylon?. Nature, 437(7063), 1243-1244.
Preprints
- A simple, sustainable route to flexible microporous carbon cloth for energy storage applications, American Chemical Society (ACS).
- Theoretical and Experimental Study of Cocoa Pod Husk Gasification in a Fixed Bed Downdraft Gasifier, Applied Energy Innovation Institute (AEii).
- Brute force determination of the optimum pore sizes for CO2 uptake, American Chemical Society (ACS).
- Calcium coordination compounds of dipicolinic and quinolinic acids: synthesis, characterization, crystal structures and DFT studies, Research Square Platform LLC.
- A small-scale gasifier-generator fueled by cocoa pod husk for rural communities in Ghana, Applied Energy Innovation Institute (AEii).
- Confirmation of Pore Formation Mechanisms in Biochars and Activated Carbons by Dual Isotherm Analysis.
- Capacity building in porous materials research for sustainable energy applications. Interface Focus, 14(4).