Professor Steven P. Armes, FRS
FRS
School of Mathematical and Physical Sciences
Firth Professor of Chemistry and Professor of Polymer and Colloid Chemistry
s.p.armes@sheffield.ac.uk
+44 114 222 9342
+44 114 222 9342
Dainton Building
Full contact details
Professor Steven P. Armes, FRS
School of Mathematical and Physical Sciences
Dainton Building
13 Brook Hill
Sheffield
S3 7HF
School of Mathematical and Physical Sciences
Dainton Building
13 Brook Hill
Sheffield
S3 7HF
- Profile
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Prof. Steve Armes obtained his BSc degree in Chemistry from the University of Bristol in 1983 and received his PhD degree from the same institution in 1987. After a postdoctoral fellowship at Los Alamos National Laboratory in New Mexico, he accepted a lectureship at Sussex University in 1989 and was promoted to a personal chair in 2000. He moved to Sheffield in 2004 to become Professor of Polymer & Colloid Chemistry.
He is currently Director of the Sheffield Polymer Centre and also serves on the board of Farapack Polymers, a University spin-out company. He was elected as a Fellow of the Royal Society in 2014 and became the first UK scientist to receive the DSM Materials Science Award in 2016. Since then, he has been awarded the 2017 ECIS-Solvay Prize, the 2018 RSC Macro Group Prize for outstanding achievement, the 2018 Royal Society Armourers and Brasiers' Company Prize, the 2020 RSC Soft Matter and Biophysical Chemistry Award, the 2020 SCI ‘Innovation in Formulation Award’ and the 2021 Sir Eric Rideal Lectureship (a lifetime achievement award).
Awards
- Royal Society/Wolfson Research Merit Award (2005-2009)
- RSC Macro Group Medal for Polymer Science (2007)
- RSC Peter Day Award for Soft Matter Research (2010)
- RSC Tilden Medal (2013)
- Fellow of the Royal Society (2014)
- RSC Interdisciplinary Prize (2014)
- RSC/SCI Thomas Graham Lecture (2014)
- German Colloid Society/Springer Colloid and Polymer Science Lectureship (2015)
- DSM Materials Science Award (2016)
- European Colloid and Interface Science (ECIS) Solvay Prize (2017)
- RSC Macro Group Medal for Outstanding Achievement (2018)
- Royal Society Armourers and Brasiers' Company Prize (2018)
- RSC Soft Matter and Biophysical Chemistry Award (2020)
- Society for Chemical Industry ‘Innovation in Formulation Award’ (2020)
- Sir Eric Rideal Lectureship (2021)
- Qualifications
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- FRS
- FRSC
- Research interests
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Research Keywords
Water-soluble polymers, block copolymers, living radical polymerisation (e.g. RAFT and ATRP), polymerisation-induced self-assembly, dispersion polymerisation, micellar self-assembly, block copolymer vesicles, biocompatible polymers, colloidal nanocomposite particles, conducting polymers, stimulus-responsive microgels, polymer-based `Pickering´ emulsifiers.
Polymer Chemistry
We use living radical polymerisation techniques such as Reversible Addition-Fragmentation chain Transfer (RAFT) and Atom Transfer Radical Polymerisation (ATRP) to synthesise a wide range of controlled-structure, methacrylate-based water-soluble polymers. Block copolymers and their micellar self-assembly in aqueous solution are of particular interest: we are currently exploring the principles of polymerisation-induced self-assembly (PISA) to prepare a range of diblock copolymer-based ‘nano-objects’ in concentrated aqueous solution.
Depending on the precise diblock copolymer curvature, such ‘nano-objects’ can possess either spherical, worm-like (see TEM image opposite) or vesicular morphologies. We now are establishing fundamental design rules for the rational design of such ‘nano-objects’ and we seek to exploit our enhanced understanding in order to generalise this powerful PISA approach to produce robust, reproducible formulations for both polar and non-polar solvents, as well as water.
Colloid Chemistry
We prepare a broad range of microscopic conducting polymer-based particles, including conducting polymer-coated latexes, conducting polymer-silica nanocomposite particles and sterically-stabilised conducting polymer particles. Such particles are proving to be useful synthetic mimics for carbonaceous and silicate-based micro-meteorites: we collaborate informally with space scientists based in the UK, Germany and the USA to aid their interpretation of data collected during various space missions (e.g. Cassini and Stardust).
Polypyrrole particles also have potential biomedical applications as contrast agents in optical coherence tomography. We have pioneered the use of ultrafine aqueous silica sols in order to prepare a range of vinyl polymer-silica nanocomposite particles. Film-forming nanocomposite compositions can be prepared using acrylic monomers, which enable the production of tough, transparent, scratch-resistant coatings.
Other recent examples include the synthesis of novel sterically-stabilised pH-responsive microgels, surface polymerisation of stimulus-responsive polymer brushes from planar surfaces and the evaluation of various latexes, microgels and nanocomposite particles as `Pickering´ emulsifiers for the production of both oil-in-water emulsions and also covalently cross-linked colloidosomes.
- Publications
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Journal articles
- Jeffamine-based diblock copolymer nanoparticles via reverse sequence polymerization-induced self-assembly in aqueous media. Polymer, 310, 127474-127474.
- Strong coupling in molecular systems: a simple predictor employing routine optical measurements. Nanophotonics, 13(14), 2453-2467. View this article in WRRO
- Synthesis and Characterization of All-Acrylic Tetrablock Copolymer Nanoparticles: Waterborne Thermoplastic Elastomers via One-Pot RAFT Aqueous Emulsion Polymerization. Chemistry of Materials, 36(4), 2061-2075.
- Determination of Reaction Kinetics by Time‐Resolved Small‐angle X‐ray Scattering during Polymerization‐Induced Self‐Assembly: Direct Evidence for Monomer‐Swollen Nanoparticles.. Angewandte Chemie International Edition, e202312119.
- Efficient synthesis of hydrolytically degradable block copolymer nanoparticles via reverse sequence polymerization‐induced self‐assembly in aqueous media. Angewandte Chemie International Edition.
- Recent Advances in Polymerization‐Induced Self‐Assembly (PISA) Syntheses in Non‐Polar Media. Angewandte Chemie International Edition, e202308372.
- Mucoadhesive Pickering Nanoemulsions via Dynamic Covalent Chemistry. Journal of Colloid and Interface Science.
- Diffusiophoresis of latex driven by anionic nanoparticles and their counterions. Journal of Colloid and Interface Science, 649, 364-371.
- Silica-coated micrometer-sized latex particles. Langmuir, 39(14), 5169-5178.
- Enhanced adsorption of epoxy‐functional nanoparticles onto stainless steel significantly reduces friction in tribological studies. Angewandte Chemie International Edition.
- Histidine‐functionalized diblock copolymer nanoparticles exhibit enhanced adsorption onto planar stainless steel. Macromolecular Rapid Communications.
- Shape-shifting thermoresponsive block copolymer nano-objects. Journal of Colloid and Interface Science, 634, 906-920.
- Time-resolved small-angle x-ray scattering studies during the aqueous emulsion polymerization of methyl methacrylate. Macromolecules, 55(22), 10188-10196.
- Synthesis of crystallizable poly(behenyl methacrylate)-based block and statistical copolymers and their performance as wax crystal modifiers. Polymer Chemistry, 13(41), 5861-5872.
- Impact ionization dust detection with compact, hollow and fluffy dust analogs. Planetary and Space Science, 220.
- Reverse sequence polymerization‐induced self‐assembly in aqueous media. Angewandte Chemie International Edition.
- Application of scattering and diffraction techniques for the morphological characterization of asphaltenes. Fuel, 327.
- Reverse Sequence Polymerization‐Induced Self‐Assembly in Aqueous Media. Angewandte Chemie.
- Tuning the Glass Transition Temperature of a Core-Forming Block during Polymerization-Induced Self-Assembly: Statistical Copolymerization of Lauryl Methacrylate with Methyl Methacrylate Provides Access to Spheres, Worms, and Vesicles. Macromolecules.
- Occlusion of Diblock Copolymer-Modified Gold Nanoparticles Generates Diabolo-Shaped Au@ZnO Nanocomposite Crystals with Enhanced Photocatalytic Properties. Chemistry of Materials, 34(7), 3357-3364.
- Reversible Addition-Fragmentation Chain Transfer Aqueous Dispersion Polymerization of 4-Hydroxybutyl Acrylate Produces Highly Thermoresponsive Diblock Copolymer Nano-Objects. Macromolecules, 55(3), 788-798.
- Polymer-Inorganic Crystalline Nanocomposite Materials via Nanoparticle Occlusion.. Macromol Rapid Commun, e2100793.
- Aldehyde-functional thermoresponsive diblock copolymer worm gels exhibit strong mucoadhesion. Chemical Science.
- Aldehyde-functional diblock copolymer nano-objects via RAFT aqueous dispersion polymerization. Biomacromolecules, 22(12), 5382-5389.
- RAFT dispersion polymerization of methyl methacrylate in mineral oil : high glass transition temperature of the core-forming block constrains the evolution of copolymer morphology. Macromolecules. View this article in WRRO
- Shape-shifting thermoreversible diblock copolymer nano-objects via RAFT aqueous dispersion polymerization of 4-hydroxybutyl acrylate. Chemical Science.
- One-pot synthesis and aqueous solution properties of pH-responsive schizophrenic diblock copolymer nanoparticles prepared via RAFT aqueous dispersion polymerization. Polymer Chemistry.
- Synthesis and aqueous solution properties of shape-shifting stimulus-responsive diblock copolymer nano-objects. Chemistry of Materials. View this article in WRRO
- RAFT aqueous emulsion polymerization of methyl methacrylate : observation of unexpected constraints when employing a non-ionic steric stabilizer block. Polymer Chemistry.
- Shear-induced alignment of block copolymer worms in mineral oil. Soft Matter.
- Synthesis of polyampholytic diblock copolymers via RAFT aqueous solution polymerization. Polymer Chemistry, 12(33), 4846-4855.
- Investigating the adsorption of anisotropic diblock copolymer worms onto planar silica and nanocellulose surfaces using a quartz crystal microbalance. Polymer Chemistry. View this article in WRRO
- Tuning the properties of hydrogen-bonded block copolymer worm gels prepared via polymerization-induced self-assembly. Chemical Science.
- Synthesis of diblock copolymer spheres, worms and vesicles via RAFT aqueous emulsion polymerization of hydroxybutyl methacrylate. Polymer Chemistry, 12(25), 3629-3639.
- Block copolymer nanoparticles are effective dispersants for micrometer-sized organic crystalline particles. ACS Applied Materials & Interfaces, 13(25), 30235-30243.
- Rational synthesis of novel biocompatible thermoresponsive block copolymer worm gels. Soft Matter, 17(22), 5602-5612.
- RAFT dispersion polymerization of N,N-dimethylacrylamide in a series of n-alkanes using a thermoresponsive poly(tert-octyl acrylamide) steric stabilizer. Polymer Chemistry. View this article in WRRO
- Small‐angle X‐ray scattering studies of block copolymer nano‐objects: Formation of ordered phases in concentrated solution during polymerization‐induced self‐assembly. Angewandte Chemie International Edition. View this article in WRRO
- Small‐angle x‐ray scattering studies of block copolymer nano‐objects : formation of ordered phases in concentrated solution during polymerization‐induced self‐assembly. Angewandte Chemie.
- Tuning the vesicle-to-worm transition for thermoresponsive block copolymer vesicles prepared via polymerisation-induced self-assembly. Polymer Chemistry, 12(9), 1224-1235.
- New aldehyde‐functional methacrylic water‐soluble polymers. Angewandte Chemie International Edition.
- Synthesis of highly transparent diblock copolymer vesicles via RAFT dispersion polymerization of 2,2,2-trifluoroethyl methacrylate in n-alkanes. Macromolecules, 54(3), 1159-1169.
- Aqueous one-pot synthesis of well-defined zwitterionic diblock copolymers by RAFT polymerization : an efficient and environmentally-friendly route to a useful dispersant for aqueous pigments. Green Chemistry, 23(3), 1248-1258.
- Time-resolved small-angle x-ray scattering studies during aqueous emulsion polymerization. Journal of the American Chemical Society, 143(3), 1474-1484. View this article in WRRO
- Synthesis and characterization of polypyrrole-coated anthracene microparticles: a new synthetic mimic for polyaromatic hydrocarbon-based cosmic dust. ACS Applied Materials & Interfaces, 13(2), 3175-3185.
- Effect of salt on the formation and stability of water-in-oil Pickering nanoemulsions stabilized by diblock copolymer nanoparticles. Langmuir, 36(51), 15523-15535.
- Pickering emulsifiers based on block copolymer nanoparticles prepared by polymerization-induced self-assembly. Langmuir, 36(51), 15463-15484.
- Oil-in-oil pickering emulsions stabilized by diblock copolymer nanoparticles. Journal of Colloid and Interface Science, 580, 354-364. View this article in WRRO
- In situ SAXS studies of a prototypical RAFT aqueous dispersion polymerization formulation: monitoring the evolution in copolymer morphology during polymerization-induced self-assembly. Chemical Science, 11(42), 11443-11454. View this article in WRRO
- RAFT dispersion polymerization of benzyl methacrylate in non-polar media using hydrogenated polybutadiene as a steric stabilizer block. Polymer Chemistry.
- Rational synthesis of epoxy-functional spheres, worms and vesicles by RAFT aqueous emulsion polymerisation of glycidyl methacrylate. Polymer Chemistry, 11(39), 6343-6355.
- Tuning the hydroxyl functionality of block copolymer worm gels modulates their thermoresponsive behavior. Polymer Chemistry, 11(31), 5040-5050.
- Exerting spatial control during nanoparticle occlusion within calcite crystals. Angewandte Chemie International Edition. View this article in WRRO
- Enthalpic incompatibility between two steric stabilizer blocks provides control over the vesicle size distribution during polymerization-induced self-assembly in aqueous media. Chemical Science. View this article in WRRO
- Efficient occlusion of nanoparticles within inorganic single crystals. Accounts of Chemical Research, 53(6), 1176-1186. View this article in WRRO
- The extent of counterion dissociation at the interface of cationic diblock copolymer nanoparticles in non-polar solvents. Journal of Colloid and Interface Science. View this article in WRRO
- Epoxy-functional diblock copolymer spheres, worms and vesicles via polymerization-induced self-assembly in mineral oil. Polymer Chemistry. View this article in WRRO
- Time-resolved small-angle neutron scattering studies of the thermally-induced exchange of copolymer chains between spherical diblock copolymer nanoparticles prepared via polymerization-induced self-assembly. Soft Matter, 16(15), 3657-3668. View this article in WRRO
- Exploring the upper size limit for sterically stabilized diblock copolymer nanoparticles prepared by polymerization-induced self-assembly in non-polar media. Langmuir, 36(14), 3730-3736. View this article in WRRO
- Synthesis of high χ–Low N diblock copolymers by polymerization‐induced self‐assembly. Angewandte Chemie International Edition. View this article in WRRO
- Synthesis of High
χ
–Low
N
Diblock Copolymers by Polymerization‐Induced Self‐Assembly. Angewandte Chemie, 132(27), 10940-10945.
- Aqueous solution behavior of stimulus-responsive poly(methacrylic acid)-poly(2-hydroxypropyl methacrylate) diblock copolymer nanoparticles. Polymer Chemistry, 11(12), 2147-2156. View this article in WRRO
- SAXS studies of the thermally-induced fusion of diblock copolymer spheres : formation of hybrid nanoparticles of intermediate size and shape. Chemical Science, 11(17), 4312-4321. View this article in WRRO
- RAFT dispersion polymerization of benzyl methacrylate in silicone oil using a silicone-based methacrylic stabilizer provides convenient access to spheres, worms, and vesicles. Macromolecules, 53(5), 1785-1794. View this article in WRRO
- Design principles for metamorphic block copolymer assemblies. Soft Matter, 16(9), 2342-2349. View this article in WRRO
- Influence of an ionic comonomer on polymerization-induced self-assembly of diblock copolymers in non-polar media. Polymer Chemistry. View this article in WRRO
- Synthesis and characterization of waterborne pyrrolidone-functional diblock copolymer nanoparticles prepared via surfactant-free RAFT emulsion polymerization. Macromolecules, 53(4), 1422-1434. View this article in WRRO
- RAFT dispersion polymerisation of lauryl methacrylate in ethanol–water binary mixtures: synthesis of diblock copolymer vesicles with deformable membranes. Polymer Chemistry. View this article in WRRO
- How do charged end-groups on the steric stabilizer block influence the formation and long-term stability of Pickering nanoemulsions prepared using sterically stabilized diblock copolymer nanoparticles?. Langmuir, 36(3), 769-780. View this article in WRRO
- Unique aqueous self-assembly behavior of a thermoresponsive diblock copolymer. Chemical Science, 11(2), 396-402. View this article in WRRO
- A worm gel-based 3D model to elucidate the paracrine interaction between multiple myeloma and mesenchymal stem cells. Materials Today Bio, 5. View this article in WRRO
- Hydroxyl-rich macromolecules enable the bio-inspired synthesis of single crystal nanocomposites. Nature Communications, 10(1). View this article in WRRO
- Ptychographic X-ray tomography reveals additive zoning in nanocomposite single crystals. Chemical Science, 11, 355-363. View this article in WRRO
- Probing the mechanism for hydrogel-based stasis induction in human pluripotent stem cells : is the chemical functionality of the hydrogel important?. Chemical Science, 11(1), 232-240. View this article in WRRO
- Cationic sterically stabilized diblock copolymer nanoparticles exhibit exceptional tolerance toward added salt. Langmuir, 35(44), 14348-14357. View this article in WRRO
- A single thermoresponsive diblock copolymer can form spheres, worms or vesicles in aqueous solution. Angewandte Chemie International Edition. View this article in WRRO
- Rationally designed anionic diblock copolymer worm gels are useful model systems for calcite occlusion studies. Polymer Chemistry, 10(37), 5131-5141. View this article in WRRO
- Block copolymer nanoparticles prepared via polymerization-induced self-assembly provide excellent boundary lubrication performance for next-generation ultralow-viscosity automotive engine oils. ACS Applied Materials & Interfaces, 11(36), 33364-33369. View this article in WRRO
- Effect of core cross-linking on the physical properties of poly(dimethylsiloxane)-based diblock copolymer worms prepared in silicone oil. Macromolecules. View this article in WRRO
- Emerging trends in polymerization-induced self-assembly. ACS Macro Letters, 8(8), 1029-1054. View this article in WRRO
- In situ small-angle X‑ray scattering studies during reversible addition−fragmentation chain transfer aqueous emulsion
polymerization. Journal of the American Chemical Society. View this article in WRRO
- Efficient occlusion of oil droplets within calcite crystals. Chemical Science. View this article in WRRO
- Self-curing super-stretchable polymer/microgel complex coacervate gels without covalent bond formation. Chemical Science, 10(38), 8832-8839. View this article in WRRO
- How Many Phosphoric Acid Units Are Required to Ensure Uniform Occlusion of Sterically‐Stabilized Nanoparticles within Calcite?. Angewandte Chemie International Edition, 58(26), 8692-8697. View this article in WRRO
- Refractive index matched, nearly hard polymer colloids. Proceedings of the Royal Society A: Mathematical, Physical and Engineering Sciences, 475(2226). View this article in WRRO
- Targeting triple-negative breast cancer cells using Dengue virus-mimicking pH-responsive framboidal triblock copolymer vesicles. Chemical Science, 10(18), 4811-4821. View this article in WRRO
- RAFT Dispersion Polymerization in Silicone Oil. Macromolecules, 52(7), 2822-2832. View this article in WRRO
- Spatially‐Controlled Occlusion of Polymer‐Stabilized Gold Nanoparticles within ZnO. Angewandte Chemie, 131(13), 4346-4351. View this article in WRRO
- End-group ionisation enables the use of poly( N -(2-methacryloyloxy)ethyl pyrrolidone) as an electrosteric stabiliser block for polymerisation-induced self-assembly in aqueous media. Polymer Chemistry, 10(11), 1312-1323. View this article in WRRO
- Spatially Controlled Occlusion of Polymer‐Stabilized Gold Nanoparticles within ZnO. Angewandte Chemie International Edition, 58(13), 4302-4307. View this article in WRRO
- Block copolymer microparticles comprising inverse bicontinuous phases prepared via polymerization-induced self-assembly. Chemical Science. View this article in WRRO
- Thermoreversible Block Copolymer Worm Gels Using Binary Mixtures of PEG Stabilizer Blocks. Macromolecules, 52(4), 1653-1662. View this article in WRRO
- What Dictates the Spatial Distribution of Nanoparticles within Calcite?. Journal of the American Chemical Society, 141(6), 2481-2489. View this article in WRRO
- Model Anionic Block Copolymer Vesicles Provide Important Design Rules for Efficient Nanoparticle Occlusion within Calcite.. Journal of the American Chemical Society, 141(6), 2557-2567. View this article in WRRO
- RAFT Dispersion Polymerization of Glycidyl Methacrylate for the Synthesis of Epoxy-Functional Block Copolymer Nanoparticles in Mineral Oil. Polymer Chemistry, 10(5), 603-611. View this article in WRRO
- Correction: Thermoreversible crystallization-driven aggregation of diblock copolymer nanoparticles in mineral oil. Chemical Science, 10(3), 947-947.
- Aqueous one-pot synthesis of epoxy-functional diblock copolymer worms from a single monomer: new anisotropic scaffolds for potential charge storage applications. Polymer Chemistry, 10(2), 194-200. View this article in WRRO
- Spin-echo small-angle neutron scattering (SESANS) studies of diblock copolymer nanoparticles. Soft Matter, 15(1), 17-21. View this article in WRRO
- Synthesis, characterization, and Pickering emulsifier performance of anisotropic cross-linked block copolymer worms: effect of aspect ratio on emulsion stability in the presence of surfactant. Langmuir. View this article in WRRO
- Anionic block copolymer vesicles act as Trojan horses to enable efficient occlusion of guest species into host calcite crystals. Chemical Science, 9(44), 8396-8401. View this article in WRRO
- Critical Dependence of Molecular Weight on Thermoresponsive Behavior of Diblock Copolymer Worm Gels in Aqueous Solution. Macromolecules, 51(21), 8357-8371. View this article in WRRO
- In Situ Spectroscopic Studies of Highly Transparent Nanoparticle Dispersions Enable Assessment of Trithiocarbonate Chain-End Fidelity during RAFT Dispersion Polymerization in Nonpolar Media. Journal of the American Chemical Society, 140(40), 12980-12988. View this article in WRRO
- Synthesis of Well-Defined Pyrrolidone-Based Homopolymers and Stimulus-Responsive Diblock Copolymers via RAFT Aqueous Solution Polymerization of 2-(N-Acryloyloxy)ethylpyrrolidone. Macromolecules, 7756-7766. View this article in WRRO
- Optimization of the high-throughput synthesis of multiblock copolymer nanoparticles in aqueous media via polymerization-induced self-assembly. Reaction Chemistry & Engineering. View this article in WRRO
- Influence of the Structure of Block Copolymer Nanoparticles on the Growth of Calcium Carbonate. Chemistry of Materials, 30(20), 7091-7099. View this article in WRRO
- Blob Size Controls Diffusion of Free Polymer in a Chemically Identical Brush in Semidilute Solution. Macromolecules, 51(16), 6312-6317. View this article in WRRO
- Can percolation theory explain the gelation behavior of diblock copolymer worms?. Chemical Science, 9(35), 7138-7144. View this article in WRRO
- Long-Term Stability of n-Alkane-in-Water Pickering Nanoemulsions: Effect of Aqueous Solubility of Droplet Phase on Ostwald Ripening. Langmuir. View this article in WRRO
- Epoxy-Functional Sterically Stabilized Diblock Copolymer Nanoparticles via RAFT Aqueous Emulsion Polymerization: Comparison of Two Synthetic Strategies. Macromolecular Rapid Communications. View this article in WRRO
- Mechanistic Insights into Diblock Copolymer Nanoparticle–Crystal Interactions Revealed via in Situ Atomic Force Microscopy. Journal of the American Chemical Society, 140(25), 7936-7945.
- pH-Responsive diblock copolymers with two different fluorescent labels for simultaneous monitoring of micellar self-assembly and degree of protonation. Polymer Chemistry, 9(21), 2964-2976. View this article in WRRO
- Synthesis of High Molecular Weight Poly(glycerol monomethacrylate) via RAFT Emulsion Polymerization of Isopropylideneglycerol Methacrylate. Macromolecules, 51(9), 3221-3232. View this article in WRRO
- Thermoreversible crystallization-driven aggregation of diblock copolymer nanoparticles in mineral oil. Chemical Science, 9(17), 4071-4082. View this article in WRRO
- Probing the local lipid environment of the Rhodobacter sphaeroides cytochrome bc1 and Synechocystis sp. PCC 6803 cytochrome b6f complexes with styrene maleic acid. Biochimica et Biophysica Acta (BBA) - Bioenergetics, 1859(3), 215-225. View this article in WRRO
- Self-Assembly of Amphiphilic Statistical Copolymers and Their Aqueous Rheological Properties. Macromolecules. View this article in WRRO
- Fabrication of microstructured binary polymer brush “corrals” with integral pH sensing for studies of proton transport in model membrane systems. Chemical Science, 9, 2238-2251. View this article in WRRO
- Using Host–Guest Chemistry to Tune the Kinetics of Morphological Transitions Undertaken by Block Copolymer Vesicles. ACS Macro Letters, 6(12), 1379-1385. View this article in WRRO
- Layer-By-Layer Self-Assembly of Polyelectrolytic Block Copolymer Worms on a Planar Substrate. Langmuir, 33(50), 14425-14436. View this article in WRRO
- Incorporation of additives in single crystals – bio-inspired approach. Acta Crystallographica Section A Foundations and Advances, 73(a1), a346-a346.
- Bespoke Diblock Copolymer Nanoparticles Enable Production of Relatively Stable Oil-in-Water Pickering Nanoemulsions.. Langmuir. View this article in WRRO
- Cross-Linking Highly Lubricious Phosphocholinated Polymer Brushes: Effect on Surface Interactions and Frictional Behavior. Macromolecules, 50(18), 7361-7371.
- Cationic disulfide-functionalized worm gels. Polymer Chemistry, 8(38), 5962-5971. View this article in WRRO
- pH-Responsive Schizophrenic Diblock Copolymers Prepared by Polymerization-Induced Self-Assembly. Macromolecules, 50(16), 6108-6116. View this article in WRRO
- Stimulus-responsive block copolymer nano-objects and hydrogels via dynamic covalent chemistry. Polymer Chemistry, 8(35), 5374-5380. View this article in WRRO
- Synthesis of well-defined epoxy-functional spherical nanoparticles by RAFT aqueous emulsion polymerization. Polymer Chemistry, 8(33), 4856-4868. View this article in WRRO
- Phenyl acrylate is a versatile monomer for the synthesis of acrylic diblock copolymer nano-objects via polymerization-induced self-assembly. Polym. Chem., 8(33), 4811-4821. View this article in WRRO
- Giant Pickering Droplets: Effect of Nanoparticle Size and Morphology on Stability. Langmuir, 33(31), 7669-7679. View this article in WRRO
- Time-Resolved SAXS Studies of the Kinetics of Thermally Triggered Release of Encapsulated Silica Nanoparticles from Block Copolymer Vesicles. Macromolecules, 50(11), 4465-4473. View this article in WRRO
- Using Dynamic Covalent Chemistry to Drive Morphological Transitions: Controlled Release of Encapsulated Nanoparticles from Block Copolymer Vesicles. Journal of the American Chemical Society, 139(22), 7616-7623. View this article in WRRO
- Micrometre and nanometre scale patterning of binary polymer brushes, supported lipid bilayers and proteins. Chem. Sci., 8(6), 4517-4526. View this article in WRRO
- Anisotropic pH-Responsive Hydrogels Containing Soft or Hard Rod-Like Particles Assembled Using Low Shear. Chemistry of Materials, 29(7), 3100-3110. View this article in WRRO
- Preparation and Cross-Linking of All-Acrylamide Diblock Copolymer Nano-Objects via Polymerization-Induced Self-Assembly in Aqueous Solution. Macromolecules, 50(4), 1482-1493. View this article in WRRO
- Synthesis of polyacid nanogels: pH-responsive sub-100 nm particles for functionalisation and fluorescent hydrogel assembly.. Soft Matter, 13(8), 1554-1560. View this article in WRRO
- Effect of Monomer Solubility on the Evolution of Copolymer Morphology during Polymerization-Induced Self-Assembly in Aqueous Solution. Macromolecules, 50(3), 796-802. View this article in WRRO
- Nanotribological properties of nanostructured poly(cysteine methacrylate) brushes. Soft Matter, 13. View this article in WRRO
- Adsorption of Small Cationic Nanoparticles onto Large Anionic Particles from Aqueous Solution: A Model System for Understanding Pigment Dispersion and the Problem of Effective Particle Density.. Langmuir. View this article in WRRO
- A Vesicle-to-Worm Transition Provides a New High-Temperature Oil Thickening Mechanism. Angewandte Chemie, 129(7), 1772-1776. View this article in WRRO
- A Vesicle-to-Worm Transition Provides a New High-Temperature Oil Thickening Mechanism.. Angewandte Chemie International Edition, 56(7), 1746-1750. View this article in WRRO
- Nanotribological Investigation of Polymer Brushes with Lithographically Defined and Systematically Varying Grafting Densities. Langmuir, 33(3), 706-713. View this article in WRRO
- H 2 O 2 Enables Convenient Removal of RAFT End-Groups from Block Copolymer Nano-Objects Prepared via Polymerization-Induced Self-Assembly in Water. Macromolecules, 50(1), 182-191. View this article in WRRO
- Poly(N-2-(methacryloyloxy)ethyl pyrrolidone)-poly(benzyl methacrylate) diblock copolymer nano-objects via RAFT alcoholic dispersion polymerisation in ethanol. Polymer, 106, 189-199. View this article in WRRO
- Cross-linked cationic diblock copolymer worms are superflocculants for micrometer-sized silica particles. Chemical Science, 7(12), 6894-6904. View this article in WRRO
- Polymer-Directed Assembly of Single Crystal Zinc Oxide/Magnetite Nanocomposites under Atmospheric and Hydrothermal Conditions. Chemistry of Materials, 28(20), 7528-7536.
- ABC Triblock Copolymer Worms: Synthesis, Characterization, and Evaluation as Pickering Emulsifiers for Millimeter-Sized Droplets. Macromolecules, 49(20), 7897-7907. View this article in WRRO
- Directed Assembly of Soft Anisotropic Nanoparticles by Colloid Electrospinning.. Macromol Rapid Commun, 37(19), 1598-1602. View this article in WRRO
- The internal structure of poly(methyl methacrylate) latexes in nonpolar solvents. Journal of Colloid and Interface Science, 479, 234-243. View this article in WRRO
- Occlusion of Sulfate-Based Diblock Copolymer Nanoparticles within Calcite: Effect of Varying the Surface Density of Anionic Stabilizer Chains. Journal of the American Chemical Society, 138(36), 11734-11742. View this article in WRRO
- RAFT Dispersion Alternating Copolymerization of Styrene with N-Phenylmaleimide: Morphology Control and Application as an Aqueous Foam Stabilizer. Macromolecules, 49(18), 6731-6742. View this article in WRRO
- Antimicrobial Graft Copolymer Gels.. Biomacromolecules, 17(8), 2710-2718. View this article in WRRO
- Stimulus-responsive non-ionic diblock copolymers: protonation of a tertiary amine end-group induces vesicle-to-worm or vesicle-to-sphere transitions. Polymer Chemistry. View this article in WRRO
- Determining the Effective Density and Stabilizer Layer Thickness of Sterically Stabilized Nanoparticles. Macromolecules. View this article in WRRO
- Bespoke contrast-matched diblock copolymer nanoparticles enable the rational design of highly transparent Pickering double emulsions. Nanoscale. View this article in WRRO
- Bespoke cationic nano-objects via RAFT aqueous dispersion polymerisation. Polym. Chem., 7(23), 3864-3873. View this article in WRRO
- Inducing an Order-Order Morphological Transition via Chemical Degradation of Amphiphilic Diblock Copolymer Nano-Objects.. Biomacromolecules. View this article in WRRO
- RAFT Aqueous Dispersion Polymerization of N -(2-(Methacryloyloxy)ethyl)pyrrolidone: A Convenient Low Viscosity Route to High Molecular Weight Water-Soluble Copolymers. Macromolecules, 49(12), 4520-4533. View this article in WRRO
- In situ small-angle X-ray scattering studies of sterically-stabilized diblock copolymer nanoparticles formed during polymerization-induced self-assembly in non-polar media. Chemical Science, 7, 5078-5090. View this article in WRRO
- Frequent mechanical stress suppresses proliferation of mesenchymal stem cells from human bone marrow without loss of multipotency. Scientific Reports, 6. View this article in WRRO
- A Robust Cross-Linking Strategy for Block Copolymer Worms Prepared via Polymerization-Induced Self-Assembly. Macromolecules, 49(8), 2928-2941. View this article in WRRO
- Streaming potential studies of the adsorption of fluorescently-labeled poly(ethylene imine) onto mica. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 494, 256-265.
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- Controlling cellular uptake by surface chemistry, size, and surface topology at the nanoscale.. Small, 5(21), 2424-2432.
- Thermo-Responsive Copolymers Based on Poly(N-isopropylacrylamide) and Poly[2-(methacryloyloxy)ethyl phosphorylcholine]: Light Scattering and Microscopy Experiments. MACROMOL CHEM PHYSIC, 210(20), 1726-1733.
- Synthesis of biocompatible sterically-stabilized poly(2-(methacryloyloxy)ethyl phosphorylcholine) latexes via dispersion polymerization in alcohol/water mixtures.. Langmuir, 25(19), 11442-11449.
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- Synthesis of Highly Branched Methacrylic Copolymers: Observation of Near-Ideal Behavior using RAFT Polymerization. MACROMOLECULES, 42(16), 5919-5924.
- Preparation of biocompatible zwitterionic block copolymer vesicles by direct dissolution in water and subsequent silicification within their membranes.. Langmuir, 25(16), 9564-9570.
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- Facile Synthesis of Well-Defined Hydrophilic Methacrylic Macromonomers Using ATRP and Click Chemistry. MACROMOLECULES, 41(24), 9542-9547.
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- Interaction of Polymer and Surfactant at the Air-Water Interface: Poly(2-(dimethylamino)ethyl methacrylate) and Sodium Dodecyl Sulfate. LANGMUIR, 24(22), 12892-12898.
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- Layer-by-layer deposition of polyelectrolyte macroinitiators for enhanced initiator density in surface-initiated ATRP.. Langmuir, 24(14), 7208-7215.
- in vitro biological evaluation of folate-functionalized block copolymer micelles for selective anti-cancer drug delivery. MACROMOL BIOSCI, 8(7), 615-626.
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- Efficient synthesis of poly(2-vinylpyridine)-silica colloidal nanocomposite particles using a cationic azo initiator.. Langmuir, 23(23), 11812-11818.
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- Direct synthesis of controlled-structure primary amine-based methacrylic polymers by living radical polymerization. MACROMOLECULES, 40(13), 4429-4438.
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- Polystyrene-silica colloidal nanocomposite particles prepared by alcoholic dispersion polymerization. CHEM MATER, 19(10), 2435-2445.
- Metal nanocrystals incorporated within pH-responsive microgel particles. LANGMUIR, 23(10), 5761-5768.
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- Esterification of hydroxylated polymers with 2-sulfobenzoic acid cyclic anhydride: A facile approach for the synthesis of near-monodisperse strong acid homopolymers and diblock copolymers. POLYMER, 48(5), 1193-1202.
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- Synthesis of zwitterionic diblock copolymers without protecting group chemistry. MACROMOLECULES, 40(2), 157-167.
- Layer-by-layer formation of smart particle coatings using oppositely charged block copolymer micelles. ADV MATER, 19(2), 247-+.
- Surface ATRP of hydrophilic monomers from ultrafine aqueous silica sols using anionic polyelectrolytic macroinitiators.. Langmuir, 23(2), 408-413.
- Synthesis of poly(2-hydroxypropyl methacrylate) latex particles via aqueous dispersion polymerization. SOFT MATTER, 3(8), 1003-1013.
- In situ observations of adsorbed microgel particles. SOFT MATTER, 3(5), 580-586.
- Synthesis of biocompatible poly[2-(methacryloyloxy)ethyl phosphorylcholine]-coated magnetite nanoparticles.. Langmuir, 22(26), 10989-10993.
- Facile synthesis of highly biocompatible poly(2-(methacryloyloxy)ethyl phosphorylcholine)-coated gold nanoparticles in aqueous solution.. Langmuir, 22(26), 11022-11027.
- Effects of copolymer concentration and chain length on the pH-responsive behavior of diblock copolymer micellar films. J COLLOID INTERF SCI, 303(2), 372-379.
- Development of branching in living radical copolymerization of vinyl and divinyl monomers. MACROMOLECULES, 39(22), 7483-7492.
- Preparation and aqueous solution properties of new thermoresponsive biocompatible ABA triblock copolymer gelators. MACROMOLECULES, 39(22), 7455-7457.
- Micelle formation and inversion kinetics of a schizophrenic diblock copolymer. MACROMOLECULES, 39(21), 7378-7385.
- Characterizing the pH-responsive behavior of thin films of diblock copolymer micelles at the silica/aqueous solution interface. LANGMUIR, 22(20), 8435-8442.
- UV irradiation-induced shell cross-linked micelles with pH-responsive cores using ABC triblock copolymers. MACROMOLECULES, 39(18), 5987-5994.
- Aqueous particulate foams stabilized solely with polymer latex particles. LANGMUIR, 22(18), 7512-7520.
- ATR-FTIR studies of a thermo-responsive ABA triblock copolymer gelator in aqueous solution. POLYMER, 47(17), 6123-6130.
- Synthesis and solid state properties of a poly(methyl methacrylate)-block-poly(2-(diethylamino)ethyl methacrylate)-block-poly(methyl methacrylate) triblock copolymer. MACROMOLECULES, 39(16), 5573-5576.
- pH-responsive diblock copolymer micelles at the silica/aqueous solution interface: Adsorption kinetics and equilibrium studies. J PHYS CHEM B, 110(30), 14744-14753.
- Stimulus-responsive particulate emulsifiers based on lightly cross-linked poly(4-vinylpyridine)-silica nanocomposite microgels.. Langmuir, 22(16), 6818-6825.
- Dynamic light scattering vs H-1 NMR investigation of pH-responsive diblock copolymers in water. MACROMOLECULES, 39(15), 5106-5112.
- Synthesis and characterisation of new shell cross-linked micelles with amine-functional coronas. EUR POLYM J, 42(7), 1487-1498.
- Long-range structural order, moiré patterns, and iridescence in latex-stabilized foams.. J Am Chem Soc, 128(24), 7882-7886.
- Synthesis and peptide-induced degradation of biocompatible fibers based on highly branched poly(2-hydroxyethyl methacrylate). ADV MATER, 18(12), 1566-+.
- Comparison of the adsorption of cationic diblock copolymer micelles from aqueous solution onto mica and silica. LANGMUIR, 22(12), 5328-5333.
- Synthesis and characterization of polypyrrole-coated sulfur-rich latex particles: New synthetic mimics for sulfur-based micrometeorites. CHEM MATER, 18(11), 2758-2765.
- Polystyrene-silica nanocomposite particles via alcoholic dispersion polymerization using a cationic azo initiator.. Langmuir, 22(11), 4923-4927.
- A New Class of Biochemically Degradable, Stimulus-Responsive Triblock Copolymer Gelators. Angewandte Chemie, 118(21), 3590-3593.
- A new class of biochemically degradable, stimulus-responsive triblock copolymer gelators.. Angew Chem Int Ed Engl, 45(21), 3510-3513.
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- Reversible activation of diblock copolymer monolayers at the interface by pH modulation, 2: Membrane interactions at the solid/liquid interface. J PHYS CHEM B, 110(18), 9177-9182.
- New folate-functionalized biocompatible block copolymer micelles as potential anti-cancer drug delivery systems. POLYMER, 47(9), 2946-2955.
- Synthesis of reversible shell cross-linked micelles for controlled release of bioactive agents. MACROMOLECULES, 39(8), 2726-2728.
- pH triggered release of protective poly(ethylene glycol)-b-polycation copolymers from liposomes. BIOMATERIALS, 27(12), 2599-2608.
- Efficient synthesis of sterically stabilized pH-responsive microgels of controllable particle diameter by emulsion polymerization.. Langmuir, 22(7), 3381-3387.
- Phosphorylcholine-based pH-responsive diblock copolymer micelles as drug delivery vehicles: Light scattering, electron microscopy, and fluorescence experiments. BIOMACROMOLECULES, 7(3), 817-828.
- Effects of pH and salt concentration on oil-in-water emulsions stabilized solely by nanocomposite microgel particles. LANGMUIR, 22(5), 2050-2057.
- Neutron reflection study of a water-soluble biocompatible diblock copolymer adsorbed at the air/water interface: The effects of pH and polymer concentration. Langmuir, 22(14), 6153-6160.
- A brief review of 'schizophrenic' block copolymers. REACT FUNCT POLYM, 66(1), 157-165.
- pH-sensitive vesicles based on a biocompatible zwitterionic diblock copolymer.. J Am Chem Soc, 127(51), 17982-17983.
- Direct imaging and spectroscopic characterization of stimulus-responsive microgels.. J Am Chem Soc, 127(48), 16808-16809.
- Synthesis and characterization of biocompatible, thermoresponsive ABC and ABA triblock copolymer gelators.. Langmuir, 21(24), 11026-11033.
- pH-induced micellization kinetics of ABC triblock copolymers measured by stopped-flow light scattering. MACROMOLECULES, 38(23), 9803-9812.
- Biomimetic stimulus-responsive star diblock gelators.. Langmuir, 21(22), 9946-9954.
- Multihydroxy polymer-functionalized carbon nanotubes: Synthesis, derivatization, and metal loading. MACROMOLECULES, 38(21), 8634-8648.
- Synthesis and chemical degradation of branched vinyl polymers prepared via ATRP: Use of a cleavable disulfide-based branching agent. MACROMOLECULES, 38(20), 8155-8162.
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- Synthesis of micrometer-sized silica-stabilized polystyrene latex particles. LANGMUIR, 21(18), 8103-8105.
- Miniemulsion polymerization of styrene using a pH-responsive cationic diblock macromonomer and its nonreactive diblock copolymer counterpart as stabilizers. LANGMUIR, 21(15), 6726-6733.
- Synthesis of branched water-soluble vinyl polymers via oxyanionic polymerization. MACROMOLECULES, 38(12), 5002-5009.
- Synthesis and characterization of branched water-soluble homopolymers and diblock copolymers using group transfer polymerization. MACROMOLECULES, 38(12), 4977-4982.
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- Synthesis and characterization of shell cross-linked micelles with hydroxy-functional coronas: a pragmatic alternative to dendrimers?. Langmuir, 21(9), 3808-3813.
- Stimulus-responsive emulsifiers based on nanocomposite microgel particles. ADV MATER, 17(8), 1014-+.
- Structural study of DNA condensation induced by novel phosphorylcholine-based copolymers for gene delivery and relevance to DNA protection. LANGMUIR, 21(8), 3591-3598.
- Synthesis and characterization of biocompatible thermo-responsive gelators based on ABA triblock copolymers.. Biomacromolecules, 6(2), 994-999.
- Effect of Varying the Oil Phase on the Behavior of pH-Responsive Latex-Based Emulsifiers: Demulsification versus Transitional Phase Inversion . Langmuir, 21(4), 1662-1662.
- Characterization of the nanomorphology of polymer-silica colloidal nanocomposites using electron spectroscopy imaging. LANGMUIR, 21(4), 1175-1179.
- Micellization in pH-sensitive amphiphilic block copolymers in aqueous media and the formation of metal nanoparticles. Faraday Discussions, 128, 129-129.
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- Use of quaternised methacrylate polymers and copolymers as catalysts and structure directors for the formation of silica from silicic acid. Journal of Materials Chemistry, 15(22), 2202-2209.
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- Solution pH-regulated interfacial adsorption of diblock phosphorylcholine copolymers. Langmuir, 21(21), 9597-9603.
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- Structure of a hydrophilic-hydrophobic block copolymer and its interactions with salt and an anionic surfactant. Langmuir, 21(11), 4856-4861.
- Synthesis of novel folic acid-functionalized biocompatible block copolymers by atom transfer radical polymerization for gene delivery and encapsulation of hydrophobic drugs. Biomacromolecules, 6(2), 1085-1096.
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- Synthesis of Polystyrene/Poly[2-(Dimethylamino)ethyl Methacrylate-stat-Ethylene Glycol Dimethacrylate] Core−Shell Latex Particles by Seeded Emulsion Polymerization and Their Application as Stimulus-Responsive Particulate Emulsifiers for Oil-in-Water Emulsions. Langmuir, 20(26), 11329-11335.
- Synthesis of Near-Monodisperse Acidic Homopolymers and Block Copolymers from Hydroxylated Methacrylic Copolymers Using Succinic Anhydride under Mild Conditions. Macromolecules, 37(24), 8903-8910.
- Phosphorylcholine–polycation diblock copolymers as synthetic vectors for gene delivery. Journal of Controlled Release, 100(2), 293-312.
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- A Zwitterionic ABC triblock copolymer that forms a "Trinity" of micellar aggregates in aqueous solution. MACROMOLECULES, 37(19), 7116-7122.
- XPS characterisation of core–shell silica–polymer composite particles synthesised by atom transfer radical polymerisation in aqueous media. European Polymer Journal, 40(9), 2129-2141.
- Effect of Varying the Oil Phase on the Behavior of pH-Responsive Latex-Based Emulsifiers: Demulsification versus Transitional Phase Inversion. Langmuir, 20(18), 7422-7429.
- The effect of poly(ethylene glycol) molecular architecture on cellular interaction and uptake of DNA complexes. Journal of Controlled Release, 97(1), 143-156.
- Synthesis of Sterically Stabilized Polystyrene Latex Particles Using Cationic Block Copolymers and Macromonomers and Their Application as Stimulus-Responsive Particulate Emulsifiers for Oil-in-Water Emulsions. Langmuir, 20(11), 4345-4354.
- Microstructure and Physical Properties of a pH-Responsive Gel Based on a Novel Biocompatible ABA-Type Triblock Copolymer. Langmuir, 20(10), 4306-4309.
- Synthesis and Characterization of Active Ester-Functionalized Polypyrrole−Silica Nanoparticles: Application to the Covalent Attachment of Proteins. Langmuir, 20(8), 3350-3356.
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- Facile Synthesis of Zwitterionic Diblock Copolymers without Protecting Group Chemistry. Macromolecules, 37(7), 2348-2352.
- Stimulus-Responsive Water-Soluble Polymers Based on 2-Hydroxyethyl Methacrylate. Macromolecules, 37(7), 2395-2403.
- Synthesis of Vinyl Polymer−Silica Colloidal Nanocomposites Prepared Using Commercial Alcoholic Silica Sols. Langmuir, 20(6), 2184-2190.
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- Synthesis of Hydrophilic Polymer-Grafted Ultrafine Inorganic Oxide Particles in Protic Media at Ambient Temperature via Atom Transfer Radical Polymerization: Use of an Electrostatically Adsorbed Polyelectrolytic Macroinitiator. Langmuir, 20(3), 587-595.
- Polymerization of sodium 4-styrenesulfonate via atom transfer radical polymerization in protic media. Polymer, 45(3), 759-768.
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- A “Holy Trinity” of Micellar Aggregates in Aqueous Solution at Ambient Temperature: Unprecedented Self-Assembly Behavior from a Binary Mixture of a Neutral−Cationic Diblock Copolymer and an Anionic Polyelectrolyte. Macromolecules, 36(26), 9994-9998.
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- Direct Synthesis of Well-Defined Quaternized Homopolymers and Diblock Copolymers via ATRP in Protic Media. Macromolecules, 36(22), 8268-8275.
- Solubilization and Controlled Release of a Hydrophobic Drug Using Novel Micelle-Forming ABC Triblock Copolymers. Biomacromolecules, 4(6), 1636-1645.
- Synthesis and Aqueous Solution Properties of Novel Sugar Methacrylate-Based Homopolymers and Block Copolymers. Biomacromolecules, 4(6), 1746-1758.
- Time of flight mass spectra of ions in plasmas produced by hypervelocity impacts of organic and mineralogical microparticles on a cosmic dust analyser. Astronomy & Astrophysics, 409(3), 1151-1167.
- Surface Polymerization of Hydrophilic Methacrylates from Ultrafine Silica Sols in Protic Media at Ambient Temperature: A Novel Approach to Surface Functionalization Using a Polyelectrolytic Macroinitiator. Advanced Materials, 15(18), 1558-1562.
- Use of sterically-stabilised polystyrene latex particles as a pH-responsive particulate emulsifier to prepare surfactant-free oil-in-water emulsionsElectronic supplementary information (ESI) available: SEM and NMR spectrum of the polystyrene latex particles. See http://www.rsc.org/suppdata/cc/b3/b304967a/. Chemical Communications(15), 1826-1826.
- Synthesis of Biocompatible, Stimuli-Responsive, Physical Gels Based on ABA Triblock Copolymers. Biomacromolecules, 4(4), 864-868.
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- Preparation and characterization of polypyrrole–silica colloidal nanocomposites in water–methanol mixtures. Journal of Colloid and Interface Science, 262(2), 418-427.
- The homo and copolymerisation of 2-(dimethylamino)ethyl methacrylate in supercritical carbon dioxide. Polymer, 44(14), 3803-3809.
- Redox Reactions of Polyaniline-Coated Latex Suspensions. Langmuir, 19(13), 5511-5516.
- Synthesis of Poly(3,4-ethylenedioxythiophene)/Silica Colloidal Nanocomposites. Langmuir, 19(11), 4523-4526.
- Well-Defined Biocompatible Block Copolymers via Atom Transfer Radical Polymerization of 2-Methacryloyloxyethyl Phosphorylcholine in Protic Media. Macromolecules, 36(10), 3475-3484.
- Synthesis and Aqueous Solution Behavior of a pH-Responsive Schizophrenic Diblock Copolymer. Langmuir, 19(10), 4432-4438.
- Effect of Polymer Ionization on the Interaction with DNA in Nonviral Gene Delivery Systems. Biomacromolecules, 4(3), 683-690.
- Synthesis of Vinyl Polymer−Silica Colloidal Nanocomposites via Aqueous Dispersion Polymerization. Langmuir, 19(6), 2072-2079.
- Synthesis and aqueous solution properties of polyelectrolyte-grafted silica particles prepared by surface-initiated atom transfer radical polymerization. Journal of Colloid and Interface Science, 257(1), 56-64.
- Synthesis and Characterization of Polypyrrole-Coated Poly(Alkyl Methacrylate) Latex Particles. Chemistry of Materials, 15(1), 233-239.
- Unexpected Transesterification of Tertiary Amine Methacrylates during Methanolic ATRP at Ambient Temperature: A Cautionary Tale. Macromolecules, 35(27), 10241-10243.
- Synthesis of low polydispersity, controlled-structure sugar methacrylate polymers under mild conditions without protecting group chemistryElectronic supplementary information (ESI) available: experimental protocols, spectroscopic characterization and rates of polymerization. See http://www.rsc.org/suppdata/cc/b2/b208654a/. Chemical Communications(23), 2776-2777.
- Synthesis of Biocompatible Polymers. 1. Homopolymerization of 2-Methacryloyloxyethyl Phosphorylcholine via ATRP in Protic Solvents: An Optimization Study. Macromolecules, 35(25), 9306-9314.
- Application of new, low density projectiles to the laboratory calibration of the Cassini Cosmic Dust Analyser (CDA), 300-304.
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- Synthesis of end-branched poly(ethylene glycol)s by aqueous atom transfer radical polymerization. Polymer Bulletin, 49(4), 235-242.
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- Determination of Reaction Kinetics by Time‐Resolved Small‐angle X‐ray Scattering during Polymerization‐Induced Self‐Assembly: Direct Evidence for Monomer‐Swollen Nanoparticles.. Angewandte Chemie.
- Synthesis of Autofluorescent Phenanthrene Microparticles via Emulsification: A Useful Synthetic Mimic for Polycyclic Aromatic Hydrocarbon-Based Cosmic Dust. ACS Applied Materials & Interfaces.
- Thermoresponsive Poly(N,N′-dimethylacrylamide)-Based Diblock Copolymer Worm Gels via RAFT Solution Polymerization: Synthesis, Characterization, and Cell Biology Applications. Biomacromolecules.
- Efficient Synthesis of Hydrolytically Degradable Block Copolymer Nanoparticles via Reverse Sequence Polymerization‐Induced Self‐Assembly in Aqueous Media. Angewandte Chemie.
- Adsorption of Aldehyde-Functional Diblock Copolymer Spheres onto Surface-Grafted Polymer Brushes via Dynamic Covalent Chemistry Enables Friction Modification. Chemistry of Materials.
- Recent Advances in Polymerization‐Induced Self‐Assembly (PISA) Syntheses in Non‐Polar Media. Angewandte Chemie.
- Synthesis and Characterization of Charge-Stabilized Poly(4-hydroxybutyl acrylate) Latex by RAFT Aqueous Dispersion Polymerization: A New Precursor for Reverse Sequence Polymerization-Induced Self-Assembly. Macromolecules.
- Sterically Stabilized Diblock Copolymer Nanoparticles Enable Efficient Preparation of Non-Aqueous Pickering Nanoemulsions. Langmuir.
- Controlled Deformation of Soft Nanogel Particles Generates Artificial Biominerals with Ordered Internal Structure. Angewandte Chemie.
- Controlled Deformation of Soft Nanogel Particles Generates Artificial Biominerals with Ordered Internal Structure. Angewandte Chemie International Edition.
- Hydrophilic Aldehyde-Functional Polymer Brushes: Synthesis, Characterization, and Potential Bioapplications. Macromolecules.
- Enhanced Adsorption of Epoxy‐Functional Nanoparticles onto Stainless Steel Significantly Reduces Friction in Tribological Studies. Angewandte Chemie.
- Microstructural Dynamics and Rheology of Worm-like Diblock Copolymer Nanoparticle Dispersions under a Simple Shear and a Planar Extensional Flow. Macromolecules.
- Adsorption of sterically-stabilized diblock copolymer nanoparticles at the oil–water interface: effect of charged end-groups on interfacial rheology. Soft Matter.
- Synthesis of High Molecular Weight Water-Soluble Polymers as Low-Viscosity Latex Particles by RAFT Aqueous Dispersion Polymerization in Highly Salty Media. Macromolecules.
- Hydrocarbon-Based Statistical Copolymers Outperform Block Copolymers for Stabilization of Ethanol–Water Foams. ACS Applied Materials & Interfaces.
- Long-Term Stability of Pickering Nanoemulsions Prepared Using Diblock Copolymer Nanoparticles: Effect of Nanoparticle Core Crosslinking, Oil Type, and the Role Played by Excess Copolymers. Langmuir.
- Synthesis of Thermoresponsive Diblock Copolymer Nano-Objects via RAFT Aqueous Emulsion Polymerization of Hydroxybutyl Methacrylate. Macromolecules.
- Differential Ablation of Organic Coatings from Micrometeoroids Simulated in the Laboratory. Journal of Geophysical Research: Planets.
- Sterically Stabilized Diblock Copolymer Nanoparticles Enable Convenient Preparation of Suspension Concentrates Comprising Various Agrochemical Actives. Langmuir.
- Highly Stretchable Conductive Covalent Coacervate Gels for Electronic Skin. Biomacromolecules.
- RAFT aqueous dispersion polymerization of 4-hydroxybutyl acrylate: effect of end-group ionization on the formation and colloidal stability of sterically-stabilized diblock copolymer nanoparticles. Polymer Chemistry, 13(5), 655-667.
- Silica nanoparticle-loaded thermoresponsive block copolymer vesicles: a new post-polymerization encapsulation strategy and thermally triggered release. Chemical Science.
- Synthesis and derivatization of epoxy-functional sterically-stabilized diblock copolymer spheres in non-polar media: does the spatial location of the epoxy groups matter?. Polymer Chemistry, 13(24), 3619-3630.
- Polymerization-induced self-assembly and disassembly during the synthesis of thermoresponsive ABC triblock copolymer nano-objects in aqueous solution. Chemical Science, 13(24), 7295-7303.
- Reverse sequence polymerization-induced self-assembly in aqueous media: a counter-intuitive approach to sterically-stabilized diblock copolymer nano-objects. Polymer Chemistry.
- In situ small-angle X-ray scattering studies during the formation of polymer/silica nanocomposite particles in aqueous solution. Chemical Science.
- New Aldehyde‐Functional Methacrylic Water‐Soluble Polymers. Angewandte Chemie.
- Site-Directed Differentiation of Human Adipose-Derived Mesenchymal Stem Cells to Nucleus Pulposus Cells Using an Injectable Hydroxyl-Functional Diblock Copolymer Worm Gel. Biomacromolecules.
- Synthesis of well-defined diblock copolymer nano-objects by RAFT non-aqueous emulsion polymerization of N-(2-acryloyloxy)ethyl pyrrolidone in non-polar media. Polymer Chemistry.
- Exerting Spatial Control During Nanoparticle Occlusion within Calcite Crystals. Angewandte Chemie.
- Highly deformable hydrogels constructed by pH-triggered polyacid nanoparticle disassembly in aqueous dispersions. Soft Matter, 14(18), 3510-3520.
- Effect of morphology on interactions between nanoparticle-stabilised air bubbles and oil droplets. Soft Matter, 14(17), 3246-3253.
- Synthesis and pH-responsive dissociation of framboidal ABC triblock copolymer vesicles in aqueous solution. Chemical Science, 9(6), 1454-1463. View this article in WRRO
- Synthesis and electrokinetics of cationic spherical nanoparticles in salt-free non-polar media. Chemical Science, 9(4), 922-934. View this article in WRRO
- Space science applications for conducting polymer particles: synthetic mimics for cosmic dust and micrometeorites. Chemical Communications, 51(95), 16886-16899. View this article in WRRO
- Live cell tracking of symmetry break in actin cytoskeleton triggered by abrupt changes in micromechanical environments. Biomaterials Science, 3(12), 1539-1544. View this article in WRRO
- Nanoscale detection of metal-labeled copolymers in patchy polymersomes. Polymer Chemistry, 6(11), 2065-2068. View this article in WRRO
- Synthesis and characterization of poly(amino acid methacrylate)-stabilized diblock copolymer nano-objects. Polymer Chemistry, 6(10), 1805-1816. View this article in WRRO
- Semi-crystalline diblock copolymer nano-objects prepared via RAFT alcoholic dispersion polymerization of stearyl methacrylate. Polymer Chemistry, 6(10), 1751-1757. View this article in WRRO
- Extent of intramolecular cyclization in RAFT-synthesized methacrylic branched copolymers using 13C NMR spectroscopy. Polymer Chemistry, 6(7), 1143-1149. View this article in WRRO
- Tuning the critical gelation temperature of thermo-responsive diblock copolymer worm gels. Polym. Chem., 5(21), 6307-6317.
- Tunable diblock copolymer micelles–adapting behaviour via subtle chemical modifications. Faraday Discuss., 128, 193-209.
- Synthesis of branched poly(methyl methacrylate)s via controlled/living polymerisations exploiting ethylene glycol dimethacrylate as branching agent. Chem. Commun.(9), 1138-1139.
- Synthesis and aqueous solution properties of a well-defined thermo-responsive schizophrenic diblock copolymer. Chem. Commun.(18), 2122-2123.
- Novel hydrophilic–hydrophilic block copolymers based on poly(vinyl alcohol). Chem. Commun.(7), 883-884.
- Synthesis of poly(pyrrole)–silica–magnetite nanocomposite particles. J. Chem. Soc., Chem. Commun.(18), 2129-2130.
- Preparation and characterisation of novel polypyrrole–silica colloidal nanocomposites. J. Mater. Chem., 4(6), 935-942.
- Novel colloidal polyaniline–silica composites. J. Chem. Soc., Chem. Commun.(2), 108-109.
- The Application of a Polypyrrole Precoat for the Metallization of Printed Circuit Boards. Journal of The Electrochemical Society, 139(1), L14-L15.
- Characterization of conducting polymer–quartz composites. J. Mater. Chem., 1(4), 525-529.
- A novel route for producing soluble polyacetylene–polyisoprene block copolymers. J. Chem. Soc., Chem. Commun.(20), 1525-1527.
- Synthesis of poly(stearyl methacrylate)-poly(2-hydroxypropyl methacrylate) diblock copolymer nanoparticles via RAFT dispersion polymerization of 2-hydroxypropyl methacrylate in mineral oil. Polymer Chemistry, 11(28), 4579-4590.
- Framboidal ABC triblock copolymer vesicles: a new class of efficient Pickering emulsifier. Chemical Science, 6(11), 6179-6188. View this article in WRRO
- Control of Particle Size in the Self-Assembly of Amphiphilic Statistical Copolymers. Macromolecules.
Chapters
- Chapter 3, New Frontiers in Colloid Science (pp. 56-69).
- A brief review of schizophrenic block copolymers, Self-Assembly (pp. 260-266).
- Polymer complexes with sugars and surfactants: Bulk and interfacial systems, Self-Assembly (pp. 187-195).
- Pyrrolidone Monomers with Acrylate Functionality and their Polymers (pp. 935-1002). Wiley
Conference proceedings papers
- 1052 Polymersomes – a Novel Drug Delivery System for the Delivery of Chemotherapeutic Agents to Oral Cancer Cells. European Journal of Cancer, Vol. 48 (pp S254-S254)
- Multi-layer films of block copolymer micelles adsorbed to colloidal templates. PHILOSOPHICAL TRANSACTIONS OF THE ROYAL SOCIETY A-MATHEMATICAL PHYSICAL AND ENGINEERING SCIENCES, Vol. 368(1927) (pp 4293-4311). Univ Liverpool, Liverpool, ENGLAND, 2 September 2009 - 4 September 2009.
- Extent of thermal ablation suffered by model organic microparticles during aerogel capture at hypervelocities. METEORITICS & PLANETARY SCIENCE, Vol. 44(10) (pp 1407-1420). Timber Cove, CA, 26 October 2008 - 28 October 2008.
- Stimulus-responsive emulsion stabilized with shell cross-linked micelles. Polymer Preprints, Japan, Vol. 55(1) (pp 1128)
- Stimulus-responsive Pickering emulsion stabilized with microgel particles. Polymer Preprints, Japan, Vol. 55(1) (pp 1127)
- Complexation of DNA with biocompatible diblock copolymers (pp 199-202)
- Block copolymers with pH-responsive poly(sodium 4-vinylbenzoate) synthesized by atom transfer radical polymerization. American Chemical Society, Polymer Preprints, Division of Polymer Chemistry, Vol. 43(2) (pp 257-258)
- Polyelectrolyte-g rafted silica particles prepared by surface-initiated atom transfer radical polymerization. American Chemical Society, Polymer Preprints, Division of Polymer Chemistry, Vol. 43(2) (pp 265-266)
- Novel polymeric surfactants synthesized by atom transfer radical polymerization. American Chemical Society, Polymer Preprints, Division of Polymer Chemistry, Vol. 43(2) (pp 49-50)
- Scanning tunneling microscopy investigation of conducting polymers. Polymeric Materials Science and Engineering, Proceedings of the ACS Division of Polymeric Materials Science and Engineering, Vol. 64 (pp 175)
- Synthesis of polymeric surfactants for the preparation of sterically-stabilized polyaniline colloids. Polymeric Materials Science and Engineering, Proceedings of the ACS Division of Polymeric Materials Science and Engineering, Vol. 60 (pp 751-756)
Preprints
- Neural Network-Driven Exploration of Solvophilic Block Size Effects in Polymerization-Induced Self-Assembly: From 2D To 3D Comprehensive Pseudo-Phase Diagram, American Chemical Society (ACS).
- XPS Depth-Profiling Studies of Chlorophyll Binding to Poly(cysteine methacrylate) Scaffolds in Pigment-Polymer Antenna Complexes using a Gas Cluster Ion Source, American Chemical Society (ACS).
- Chlorophyll Binding to Poly(cysteine methacrylate) Scaffolds in Pigment-Polymer Antenna Complexes studied by Depth-Profiling X-Ray Photoelectron Spectroscopy with a Gas Cluster Ion Source, American Chemical Society (ACS).
- Phage display against two-dimensional metal-organic nanosheets as a new route to highly selective biomolecular recognition surfaces, American Chemical Society (ACS).
- Jeffamine-based diblock copolymer nanoparticles via reverse sequence polymerization-induced self-assembly in aqueous media. Polymer, 310, 127474-127474.
- Teaching activities
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Undergraduate and postgraduate taught modules
- Chemistry and the World Around Us (Level 1): Paint Technology and Laundry Science; Hair Products, Sunscreens and Cosmetics; Chocolate, Ice Cream, Paper and Water.
- Introducing some simple chemical principles of familiar aspects of the world around us which we often take for granted and to highlight the significance of chemistry to everyday life, society, and the future of our planet.
- Fundamentals of Polymer Science (Levels 3 & 4)
This course forms an introduction to polymer science, including topics such as: nomenclature; molecular weight; solid-state properties; different types of polymerisation. - Colloid Science (Level 3)
This course is an introduction to colloid science, covering topics such as: classification of colloids; particle size analysis; adsorption of amphiphilic molecules at the air/water interface; emulsions and microemulsions. - Fundamental Polymer Chemistry (Postgraduate Level)
This course forms an introduction to polymer science for post-graduate students, including topics such as: nomenclature; molecular weight; solid-state properties; different types of polymerisation.
Laboratory Teaching:
- Level 4 Research Project