Dr Marco Conte
School of Mathematical and Physical Sciences
Lecturer in Physical Chemistry
+44 114 222 9506
Full contact details
School of Mathematical and Physical Sciences
Dainton Building
13 Brook Hill
Sheffield
S3 7HF
- Profile
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Dr. Marco Conte is a chemist who specialises in analytical chemistry, physical chemistry, and catalysis, mainly focused on scale-up applications. He completed his Laurea in Chemistry at the University of Padova in 2003, followed by a PhD at Cardiff University in 2006. Dr. Conte’s postdoctoral work includes positions at leading institutions: he served as a Research Associate at the University of York (2006-2009), Cardiff School of Chemistry (2010-2011), and the Cardiff Catalysis Institute (2011-2013), and as a research visitor at the Rutherford Appleton Laboratories (2013-2014), where he deepened his expertise in catalytic processes.
In 2013, Dr. Conte joined the University of Sheffield as a lecturer, initially focusing on teaching. In 2014, his role expanded to include research in physical chemistry and catalysis. He is currently serving as an editorial board member for the Molecular Catalysis journal.
- Qualifications
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- MRSC
- FHEA
- Research interests
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Dr Conte is widely recognized for his extensive research in the development of novel heterogeneous catalysts for sustainable chemical processes. His work addresses key areas such as fine chemical synthesis, hydrogen production, hydrocarbon oxidation, water treatment, biomass-to-fuel conversion, and waste valorisation. This is achieved by developing materials that are either thermally of photochemically activated.
A major focus of his research lies in identifying structural/activity correlations, which he pursues through advanced analytical chemistry and method development. His lab utilizes a diverse array of spectroscopic and characterization techniques, including magnetic resonance spectroscopies (NMR and EPR), optical spectroscopies (IR, Raman), thermal analysis (TGA), chromatographic techniques (GC/MS), surface science methods (XPS), bulk solid analysis (XRPD and in situ XRD), and elemental analysis (ICP).
Dr. Conte’s groundbreaking work with metal nanoparticles, metal oxides, and microporous materials, combined with his expertise in developing in situ spectroscopies for catalysis, has resulted in over 50 influential publications. With an H-index of 30 and more than 4,000 citations, his research has been repeatedly featured in prestigious scientific journals, underscoring the far-reaching impact and innovation of his work.
- Publications
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Journal articles
- Interface Synergy of Exposed Oxygen Vacancy and Pd Lewis Acid Sites Enabling Superior Cooperative Photoredox Synthesis. Angewandte Chemie International Edition, e202412707.
- Exploring Homolytic Aromatic Substitution as a Driver for Fuel Deposition with Quantum Chemistry and Experiments. Fuel, 360, 130470-130470.
- Low-field 2D NMR relaxation and DRIFTS studies of glucose isomerization in zeolite Y: New insights into adsorption effects on catalytic performance. Journal of Catalysis, 425, 269-285.
- New Radical Route and Insight for Highly Efficient Benzimidazoles Synthesis Integrated with Hydrogen Evolution. Angewandte Chemie International Edition, e202304306.
- Conversion of glucose to fructose over Sn and Ga-doped zeolite Y in methanol and water media. Applied Catalysis A: General, 642.
- Cooperative Coupling of Oxidative Organic Synthesis and Hydrogen Production over Semiconductor-Based Photocatalysts.. Chem Rev.
- The acoustical properties of tetraethyl orthosilicate based granular silica aerogels. The Journal of the Acoustical Society of America, 149(6), 4149-4158.
- Rationally designed transition metal hydroxide nanosheet arrays on graphene for artificial CO2 reduction. Nature Communications, 11.
- The role of impurities in the La2O3 catalysed carboxylation of crude glycerol. Catalysis Letters. View this article in WRRO
- Novel rhodium on carbon catalysts for the oxidation of benzyl alcohol to benzaldehyde: A study of the modification of metal/support interactions by acid pre-treatments. Applied Catalysis A: General, 570, 271-282. View this article in WRRO
- Water as a catalytic switch in the oxidation of aryl alcohols by polymer incarcerated rhodium nanoparticles. Catal. Sci. Technol., 7(18), 3985-3998. View this article in WRRO
- Catalytic Partial Oxidation of Cyclohexane by Bimetallic Ag/Pd Nanoparticles on Magnesium Oxide. Chemistry, 23(49), 11834-11842. View this article in WRRO
- Mechanism of Hydrogen-Bonded Complex Formation between Ibuprofen and Nanocrystalline Hydroxyapatite. Langmuir, 33(12), 2965-2976. View this article in WRRO
- Dynamic NMR and Quantum-Chemical Study of the Stereochemistry and Stability of the Chiral MoO2(acac)2 Complex in Solution. The Journal of Physical Chemistry A, 120(34), 6677-6687. View this article in WRRO
- Investigation of the active species in the carbon-supported gold catalyst for acetylene hydrochlorination. Catalysis Science and Technology, 6(13), 5144-5153.
- Insights into the Reaction Mechanism of Cyclohexane Oxidation Catalysed by Molybdenum Blue Nanorings. Catalysis Letters, 146(1), 126-135. View this article in WRRO
- Acoustical characterization of nano-porous carbons. The Journal of the Acoustical Society of America, 138(3), 1885-1885.
- Liquid phase oxidation of cyclohexane using bimetallic Au–Pd/MgO catalysts. Applied Catalysis A: General, 504, 373-380. View this article in WRRO
- Oxidation of Benzyl Alcohol and Carbon Monoxide Using Gold Nanoparticles Supported on MnO Nanowire Microspheres. Chemistry - A European Journal.
- Characterization of Au3+ species in Au/C catalysts for the hydrochlorination reaction of acetylene. Catalysis Letters, 144(1), 1-8. View this article in WRRO
- Tungstate promoted vanadium phosphate catalysts for the gas phase oxidation of methanol to formaldehyde. Catalysis Science and Technology, 3(6), 1558-1564.
- Aqua regia activated Au/C catalysts for the hydrochlorination of acetylene. Journal of Catalysis, 297, 128-136.
- Modifications of the metal and support during the deactivation and regeneration of Au/C catalysts for the hydrochlorination of acetylene. Catalysis Science and Technology, 3(1), 128-134.
- ChemInform Abstract: Hydrochlorination of Acetylene Catalyzed by Gold. ChemInform, 43(52), no-no.
- Cyclohexane oxidation using Au/MgO: an investigation of the reaction mechanism.. Phys Chem Chem Phys, 14(47), 16279-16285.
- Enhanced selectivity to propene in the methanol to hydrocarbons reaction by use of ZSM-5/11 intergrowth zeolite. Microporous and Mesoporous Materials, 164, 207-213.
- Reactivity of Ga
2 O3 clusters on zeolite ZSM-5 for the conversion of methanol to aromatics. Catalysis Letters, 142(9), 1049-1056. - Non-lattice surface oxygen species implicated in the catalytic partial oxidation of decane to oxygenated aromatics.. Nat Chem, 4(2), 134-139.
- Modified zeolite ZSM-5 for the methanol to aromatics reaction. Catalysis Science and Technology, 2(1), 105-112.
- Controlling vanadium phosphate catalyst precursor morphology by adding alkane solvents in the reduction step of VOPO
4 ·2H2 O to VOHPO4 ·0.5H2 O. Journal of Materials Chemistry, 21(40), 16136-16146. - Selective oxidation of glycerol by highly active bimetallic catalysts at ambient temperature under base-free conditions. Angewandte Chemie - International Edition, 50(43), 10136-10139.
- Selective Oxidation of Glycerol by Highly Active Bimetallic Catalysts at Ambient Temperature under Base-Free Conditions. Angewandte Chemie, 123(43), 10318-10321.
- A catalytic reactor for the trapping of free radicals from gas phase oxidation reactions.. Rev Sci Instrum, 81(10), 104102.
- Spin trapping of radical intermediates in gas phase catalysis: cyclohexane oxidation over metal oxides.. Chem Commun (Camb), 46(22), 3991-3993.
- Cyanogen formation during asymmetric cyanohydrin synthesis.. Chem Commun (Camb), 46(19), 3372-3374.
- Enhanced acyl radical formation in the Au nanoparticle-catalysed aldehyde oxidation.. Chem Commun (Camb), 46(1), 145-147.
- Corrigendum to “Hydrochlorination of acetylene using supported bimetallic Au-based catalysts” [J. Catal. 257 (2008) 190–198]. Journal of Catalysis, 266(1), 164-164.
- Mechanistic insight into TEMPO-inhibited polymerisation: simultaneous determination of oxygen and inhibitor concentrations by EPR.. Org Biomol Chem, 7(13), 2685-2687.
- Spin trapping of Au-H intermediate in the alcohol oxidation by supported and unsupported gold catalysts.. J Am Chem Soc, 131(20), 7189-7196.
- Radical intermediates in chloroform reactions over triphenylphosphine-protected Au nanoparticles.. Org Biomol Chem, 7(7), 1361-1367.
- Reactivation of a carbon-supported gold catalyst for the hydrochlorination of acetylene. Catalysis Letters, 124(3-4), 165-167.
- Hydrochlorination of acetylene using supported bimetallic Au-based catalysts. Journal of Catalysis, 257(1), 190-198.
- Selective formation of chloroethane by the hydrochlorination of ethene using zinc catalysts. JOURNAL OF CATALYSIS, 252(1), 23-29.
- Gold nanoparticle-initiated free radical oxidations and halogen abstractions.. Org Biomol Chem, 5(21), 3504-3509.
- Hydrochlorination of acetylene using a supported gold catalyst: A study of the reaction mechanism. Journal of Catalysis, 250(2), 231-239.
- Chemically induced fast solid-state transitions of omega-VOPO4 in vanadium phosphate catalysts.. Science, 313(5791), 1270-1273.
- Unexpected promotion of Au/TiO
2 by nitrate for CO oxidation. Chemical Communications(18), 2351-2353. - Interface Synergy of Exposed Oxygen Vacancy and Pd Lewis Acid Sites Enabling Superior Cooperative Photoredox Synthesis. Angewandte Chemie.
- Bimetallic Single Atom/Nanoparticle Ensemble for Efficient Photochemical Cascade Synthesis of Ethylene from Methane. Angewandte Chemie International Edition.
- Bimetallic Single Atom/Nanoparticle Ensemble for Efficient Photochemical Cascade Synthesis of Ethylene from Methane. Angewandte Chemie.
- Selective Imines Synthesis by Designing an Atomic-Level Cu–Pt Electron Transfer Channel over CdS Nanosheets. ACS Catalysis, 657-669.
- New Radical Route and Insight for Highly Efficient Benzimidazoles Synthesis Integrated with Hydrogen Evolution. Angewandte Chemie.
- Engineering Semiconductor Quantum Dots for Selectivity Switch on High-Performance Heterogeneous Coupling Photosynthesis. ACS Nano.
- Catalytic oxygen activation versus autoxidation for industrial applications: a physicochemical approach. Physical Chemistry Chemical Physics, 17(2), 715-731. View this article in WRRO
- Energy dispersive X-ray spectroscopy of bimetallic nanoparticles in an aberration corrected scanning transmission electron microscope. FARADAY DISCUSSIONS, 138, 337-351. View this article in WRRO
- Sensing aromatic pollutants in water with catalyst-sensitized water-gated transistor. Chemical Papers. View this article in WRRO
- Molybdenum blue nano-rings: an effective catalyst for the partial oxidation of cyclohexane. Catalysis Science & Technology, 5(1), 217-227. View this article in WRRO
Chapters
- Hydrochlorination of acetylene catalyzed by gold In Hashmi ASK & Toste FD (Ed.), Modern Gold Catalyzed Synthesis Wiley-VCH
Conference proceedings papers
- Teaching interests
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Physical chemistry, analytical chemistry, industrial catalysis, cleaner production, communication for sustainable researchers
- Teaching activities
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Undergraduate taught modules
- Chemistry at surfaces (Year 3)
This segment focuses on the study of chemical reactions and processes that occur at the interface between two or more phases.
Postgraduate taught modules
- The physical chemistry of heterogeneous catalysis (Year 4 and MSc)
This course is focused on the description and application of physical chemistry principles that are at the basis of heterogeneous catalysis, and applied to relevant industrial processes. - Sustainable Technologies (Year 4 and MSc)
This module analyses a series of chemical processes aimed at the manufacturing of commodities and how to reduce their environmental impact - Communication for sustainable researchers (Year 4 and MSc)
This module explores how to translate complex scientific information focused on life cycle analysis and sustainability in an accurate manner to a lay audience by using multimedia tools.
Support Teaching:
- Level 3 Literature Review
Laboratory Teaching:
- Level 2 and Level 3 Physical chemistry laboratories
- Level 4 Research Project
- Chemistry at surfaces (Year 3)