Professor Goran Ungar
BSc PhD CPhys
School of Chemical, Materials and Biological Engineering
Emeritus Professor of Polymers and Organic Materials
Full contact details
School of Chemical, Materials and Biological Engineering
Sir Robert Hadfield Building
Mappin Street
Sheffield
S1 3JD
- Research interests
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Two main research areas: The first is the study of structure and phase behaviour of liquid crystalline (l.c.) and supramolecular polymeric and low molecular systems. Molecular organisation is investigated by diffraction, microscopy and spectroscopy. Applying principles of self-assembly, new molecular architectures are designed and tested in collaboration with synthetic chemists. Current topics include molecular channel matrices, liquid crystalline (LC) dendrimers and amphiphiles, soft quasicrystals, novel thermotropic l.c. phases with 2d and 3d periodicity ("micellar", bicontinuouscubic and non-cubic, columnar, honeycomb), controlled shape supramolecularnano-objects, helical self-assembly of organic semiconductors, LC-directed superlattices of metal and semiconductor nanoparticles for photonic and metamaterials, nano-confined LCs highly conducting polymer electrolytes.
The second area of research is structure and morphology of semicrystalline polymers. In particular, monodisperse model polymers in the form of very long n-alkanes are studied. As a result of these studies the "self-poisoning" crystallization mechanisms has been proposed for flexible polymers. Furthermore, new layer structures and superlattices were discovered. New mathematical models allowed us to describe quantitatively the shapes of polymer crystals. We study structure and structure formation of biodegradable and light-emitting polymers, and investigate structure, morphology, and structure formation in semicrystalline polymers, including biodegradable polyesters and copolyesters, as well as in bulk and thin-film nanocomposites containing nanoparticles, nanofibres and graphene.
The development of advanced instrumentation and analytical methods for x-ray and neutron scattering, specifically tailored for liquid crystal and polymer studies, plays a major part in the group's research. Low and wide angle scattering X-ray detectors are incorporated into purpose-built in-house equipment. Synchrotron experiments are carried out where high source brilliance and high resolution are required. Grazing-incidence small- and wide-angle scattering experiments are carried out at ESRF and Diamond synchrotrons and neutron diffraction at ISIS and ILL. Diffraction techniques are complemented with microscopies: optical, TEM, SEM and, in particular, high-resolution AFM.
Much of the research is done in collaboration with Dr. X.B. Zeng.
Key projects:
- Project Leader of the SCALES network “Complexity across lengthscales in soft matter” funded by European Science Foundation.
- European FP7 project “Self-Organized Nanomaterials for Tailored Optical and Electrical Properties - NANOGOLD”.
- “Materials for Renewable Energy Nature's Way (RENEW)” (PIRE scheme, NSF-EPSRC).
- Publications
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Journal articles
- X-ray diffraction on smectic liquid crystals: Determining molecular arrangement from diffraction intensities. Journal of Molecular Liquids, 126866-126866.
- Quantitative Model of Multiple Crystal Growth Rate Minima in Polymers with Regularly Spaced Substituent Groups. Macromolecules, 57(4), 1667-1676.
- Reentrant 2D Nanostructured Liquid Crystals by Competition between Molecular Packing and Conformation: Potential Design for Multistep Switching of Ionic Conductivity. ChemPhysChem, 24(8).
- Front Cover: Reentrant 2D Nanostructured Liquid Crystals by Competition between Molecular Packing and Conformation: Potential Design for Multistep Switching of Ionic Conductivity (ChemPhysChem 8/2023). ChemPhysChem, 24(8).
- Effect of mesogenic corona on type and anisotropy of gold nanoparticle superlattice: when can tail wag the dog?. Chemistry – A European Journal.
- A regime beyond the Hall–Petch and inverse-Hall–Petch regimes in ultrafine-grained solids. Communications Physics, 5.
- Understanding and Manipulating Helical Nanofilaments in Binary Systems with Achiral Dopants.. Nano Lett.
- Temperature and Stress -resistant Solid State Electrolyte for Stable Lithium-Metal Batteries. Energy Storage Materials.
- Front Cover: Self‐assembly of Gold Nanoparticles into an Adjustable Plasmonic 3D Lattice using Janus‐type Forked Mesogenic Ligands (Chem. Asian J. 8/2022). Chemistry – An Asian Journal, 17(8).
- Self-organization of rectangular bipyramidal helical columns by supramolecular orientational memory epitaxially nucleated from a Frank-Kasper σ phase. Giant, 9. View this article in WRRO
- A case of antiferrochirality in a liquid crystal phase of counter-rotating staircases. Nature Communications, 13(1).
- Bowls, vases and goblets—the microcrockery of polymer and nanocomposite morphology revealed by two-photon optical tomography. Nature Communications, 12(1). View this article in WRRO
- Nearly monodisperse unimolecular micelles via chloro-based atom transfer radical polymerization. Giant, 7, 100062-100062.
- Quasi-continuous melting of model polymer monolayers prompts reinterpretation of polymer melting. Nature Communications, 12(1). View this article in WRRO
- The statistics of the ordering of chiral ribbons on a honeycomb lattice. Journal of Statistical Mechanics: Theory and Experiment, 2021(8), 083203-083203. View this article in WRRO
- Frustrated Layered Self-Assembly Induced Superlattice from Two-Dimensional Nanosheets. Nano Letters, 20(12), 8647-8653.
- Supramolecular Networks: Helical Networks of π‐Conjugated Rods – A Robust Design Concept for Bicontinuous Cubic Liquid Crystalline Phases with Achiral
Ia
3¯
d
and Chiral
I
23 Lattice (Adv. Funct. Mater. 45/2020). Advanced Functional Materials, 30(45), 2070298-2070298.
- Helical networks of π‐conjugated rods – a robust design concept for bicontinuous cubic liquid crystalline phases with Ia3d and chiral I23 lattice. Advanced Functional Materials. View this article in WRRO
- Tailoring liquid crystal honeycombs by head-group choice in bird-like bent-core mesogens. Journal of Materials Chemistry C. View this article in WRRO
- Extraordinary Acceleration of Cogwheel Helical Self-Organization of Dendronized Perylene Bisimides by the Dendron Sequence Encoding Their Tertiary Structure. Journal of the American Chemical Society, 142(20), 9525-9536.
- Luminescent Metallacycle‐Cored Liquid Crystals Induced by Metal Coordination. Angewandte Chemie, 132(25), 10229-10236.
- Luminescent metallacycle‐cored liquid crystals induced by metal coordination. Angewandte Chemie International Edition. View this article in WRRO
- Liquid Organic Frameworks: The Single-Network “Plumber’s Nightmare” Bicontinuous Cubic Liquid Crystal. Journal of the American Chemical Society, 142(7), 3296-3300.
- Chirality Induction through Nano‐Phase Separation: Alternating Network Gyroid Phase by Thermotropic Self‐Assembly of X‐Shaped Bolapolyphiles. Angewandte Chemie, 132(7), 2747-2751.
- Chirality induction through nano-phase separation: Alternating network gyroid (I4132) phase by thermotropic self-assembly of X-shaped bolapolyphiles. Angewandte Chemie International Edition, 59(7), 2725-2729. View this article in WRRO
- Fluorescence microscopy tracking of dyes, nanoparticles and quantum dots during growth of polymer spherulites. Polymer, 191, 122246-122246.
- A self-assembled liquid crystal honeycomb of highly stretched (3-1-1)-hexagons. Chemical Communications, 2020(1), 62-65. View this article in WRRO
- New type of columnar liquid crystal superlattice in double‐taper ionic minidendrons. Chemistry – A European Journal, 25(60), 13739-13747. View this article in WRRO
- Sequence-Defined Dendrons Dictate Supramolecular Cogwheel Assembly of Dendronized Perylene Bisimides. Journal of the American Chemical Society, 141(40), 15761-15766.
- Cover Feature: New Type of Columnar Liquid Crystal Superlattice in Double‐Taper Ionic Minidendrons (Chem. Eur. J. 60/2019). Chemistry – A European Journal, 25(60), 13651-13651. View this article in WRRO
- Corrigendum to “In situ synthesis of monoclinic β-Ga2O3 nanowires on flexible substrate and solar-blind photodetector” [J. Alloy. Comp. 787 (2019) 133–139]. Journal of Alloys and Compounds, 807, 151768-151768.
- A Self‐Assembled Bicontinuous Cubic Phase with a Single‐Diamond Network. Angewandte Chemie, 131(22), 7453-7457.
- A self-assembled bicontinuous cubic phase with a single-diamond network. Angewandte Chemie International Edition, 58(22), 7375-7379. View this article in WRRO
- In situ synthesis of monoclinic β-Ga2O3 nanowires on flexible substrate and solar-blind photodetector. Journal of Alloys and Compounds, 787, 133-139.
- An Ising transition of chessboard tilings in a honeycomb liquid crystal. Molecular Systems Design and Engineering, 4(2), 396-406. View this article in WRRO
- Soft self-assembled sub-5 nm scale chessboard and snub-square tilings with oligo(para-phenyleneethynylene) rods. Chemical Communications, 55(29), 4154-4157. View this article in WRRO
- Square and Hexagonal Columnar Liquid Crystals Confined in Square and Triangular Pores. Advanced Functional Materials, 29(3), 1806078-1806078.
- Dendronized Poly(2-oxazoline) Displays within only Five Monomer Repeat Units Liquid Quasicrystal, A15 and σ Frank–Kasper Phases. Journal of the American Chemical Society, 140(49), 16941-16947.
- Soft Rectangular Sub-5 nm Tiling Patterns by Liquid Crystalline Self-Assembly of T-Shaped Bolapolyphiles. Advanced Functional Materials, 28(46). View this article in WRRO
- Transition between tangential and co-axial liquid crystalline honeycombs in the self-assembly of Y-shaped bolapolyphiles. Chemical Communications, 54(87), 12306-12309. View this article in WRRO
- Molecular ejection transition in liquid crystal columns self-assembled from wedge-shaped minidendrons. Soft Matter. View this article in WRRO
- Lamellar Liquid Crystals of In-Plane Lying Rod-Like Mesogens with Designer Side-Chains: the Case of Sliding vs Locked Layers. Chemistry - A European Journal, 24(60), 16072-16084. View this article in WRRO
- Dynamic calorimetry and XRD studies of the nematic and twist-bend nematic phase transitions in a series of dimers with increasing spacer length. Physical Chemistry Chemical Physics, 20(39), 25268-25274. View this article in WRRO
- Hierarchical Self-Organization of Chiral Columns from Chiral Supramolecular Spheres. Journal of the American Chemical Society, 140(41), 13478-13487.
- Structure, morphology, and nonlinear optical properties of orthorhombic α-Ca(HCOO)2 single crystals. Optical Materials Express, 8(8), 2238-2238.
- Innenrücktitelbild: The Solution of the Puzzle of Smectic-Q: The Phase Structure and the Origin of Spontaneous Chirality (Angew. Chem. 11/2018). Angewandte Chemie, 130(11), 3029-3029.
- Inside Back Cover: The Solution of the Puzzle of Smectic-Q: The Phase Structure and the Origin of Spontaneous Chirality (Angew. Chem. Int. Ed. 11/2018). Angewandte Chemie International Edition, 57(11), 2977-2977. View this article in WRRO
- The solution of the puzzle of smectic-Q: The phase structure and the origin of spontaneous chirality. Angewandte Chemie, 130(11), 2885-2890. View this article in WRRO
- The Solution of the Puzzle of Smectic-Q: The Phase Structure and the Origin of Spontaneous Chirality. Angewandte Chemie - International Edition, 57(11), 2835-2840. View this article in WRRO
- Twist-bend nematic phase in biphenylethane-based copolyethers. Soft Matter, 14(16), 3003-3011. View this article in WRRO
- Trigonal columnar self-assembly of bent phasmid mesogens. Chemical Communications, 54(2), 156-159. View this article in WRRO
- Mesoscale Graphene-like Honeycomb Mono- and Multilayers Constructed via Self-Assembly of Coclusters. J Am Chem Soc.
- Direct AFM observation of individual micelles, tile decorations and tiling rules of a dodecagonal liquid quasicrystal. Journal of Physics: Condensed Matter, 29(41). View this article in WRRO
- Solvent diffusion in polymer-embedded hollow nanoparticles studied by in situ small angle X-ray scattering.. Phys Chem Chem Phys, 19(32), 21663-21671.
- Monte Carlo study of the ordering in a strongly frustrated liquid crystal. Physical Review E, 95(6). View this article in WRRO
- A Low-Symmetry Cubic Mesophase of Dendronized CdS Nanoparticles and Their Structure-Dependent Photoluminescence. Chem, 2(6), 860-876. View this article in WRRO
- Diverse configurations of columnar liquid crystals in cylindrical nano- and micropores.. Soft Matter, 22(13), 4122-4131. View this article in WRRO
- Molecular organization in the twist–bend nematic phase by resonant X-ray scattering at the Se K-edge and by SAXS, WAXS and GIXRD. Physical Chemistry Chemical Physics, 19(21), 13449-13454. View this article in WRRO
- Screening Libraries of Semifluorinated Arylene Bisimides to Discover and Predict Thermodynamically Controlled Helical Crystallization. ACS Combinatorial Science, 18(12), 723-739.
- Body-centred cubic packing of spheres – the ultimate thermotropic assembly mode for highly divergent dendrons. Nanoscale Horizons, 2(1), 43-49. View this article in WRRO
- Formation of a Double Diamond Cubic Phase by Thermotropic Liquid Crystalline Self‐Assembly of Bundled Bolaamphiphiles. Angewandte Chemie, 128(29), 8464-8467.
- Formation of a Double Diamond Cubic Phase by Thermotropic Liquid Crystalline Self-Assembly of Bundled Bolaamphiphiles.. Angew Chem Int Ed Engl, 55(29), 8324-8327. View this article in WRRO
- Added Alkane Allows Thermal Thinning of Supramolecular Columns by Forming Superlattice—An X-ray and Neutron Study. Journal of the American Chemical Society, 138(18), 5757-5760. View this article in WRRO
- Structural, magnetic and electrical transport properties of double perovskite Tb2MnCoO6. Journal of Materials Research, 31(8), 1038-1045.
- A theoretical study of dispersion-to-aggregation of nanoparticles in adsorbing polymers using molecular dynamics simulations. Nanoscale, 8(13), 6964-6968.
- Cover Picture: Mirror Symmetry Breaking by Chirality Synchronisation in Liquids and Liquid Crystals of Achiral Molecules (ChemPhysChem 1/2016). ChemPhysChem, 17(1), 1-1.
- Mirror Symmetry Breaking by Chirality Synchronisation in Liquids and Liquid Crystals of Achiral Molecules. ChemPhysChem, 17(1), 3-3.
- A supramolecular helix that disregards chirality. Nature Chemistry, 8(1), 80-89. View this article in WRRO
- Zeolite-like liquid crystals. Nature Communications, 6(1). View this article in WRRO
- Ionic Switch Induced by a Rectangular–Hexagonal Phase Transition in Benzenammonium Columnar Liquid Crystals. Journal of the American Chemical Society, 137(41), 13212-13215. View this article in WRRO
- Crystal structure and electrical transport properties of polycrystalline TbMn1−Fe O3. Journal of Physics and Chemistry of Solids, 85, 81-85.
- Helically Twisted Chiral Arrays of Gold Nanoparticles Coated with a Cholesterol Mesogen. Journal of the American Chemical Society, 137(40), 12736-12739. View this article in WRRO
- Mirror Symmetry Breaking by Chirality Synchronisation in Liquids and Liquid Crystals of Achiral Molecules. ChemPhysChem, 17(1), 9-26.
- Rheology of Thermotropic Liquid-Crystalline Dendron-Modified Gold Nanoparticles. Molecular Crystals and Liquid Crystals, 617(1), 50-57.
- Increasing 3D Supramolecular Order by Decreasing Molecular Order. A Comparative Study of Helical Assemblies of Dendronized Nonchlorinated and Tetrachlorinated Perylene Bisimides. Journal of the American Chemical Society, 137(15), 5210-5224. View this article in WRRO
- Columnar Liquid Crystals in Cylindrical Nanoconfinement. ACS Nano, 9(2), 1759-1766. View this article in WRRO
- Complex Columnar Hexagonal Polymorphism in Supramolecular Assemblies of a Semifluorinated Electron-Accepting Naphthalene Bisimide. Journal of the American Chemical Society, 137(2), 807-819. View this article in WRRO
- Dynamic Mirror-Symmetry Breaking in Bicontinuous Cubic Phases. Angewandte Chemie, 126(48), 13331-13336.
- Inside Back Cover: Dynamic Mirror-Symmetry Breaking in Bicontinuous Cubic Phases (Angew. Chem. Int. Ed. 48/2014). Angewandte Chemie International Edition, 53(48), 13293-13293.
- Innenrücktitelbild: Dynamic Mirror-Symmetry Breaking in Bicontinuous Cubic Phases (Angew. Chem. 48/2014). Angewandte Chemie, 126(48), 13509-13509.
- Dynamic Mirror‐Symmetry Breaking in Bicontinuous Cubic Phases. Angewandte Chemie International Edition, 53(48), 13115-13120. View this article in WRRO
- Skeletal cubic, lamellar, and ribbon phases of bundled thermotropic bolapolyphiles. Journal of the American Chemical Society, 136(19), 6846-6849.
- Homochiral columns constructed by chiral self-sorting during supramolecular helical organization of hat-shaped molecules.. J Am Chem Soc, 136(19), 7169-7185. View this article in WRRO
- Honeycombs in honeycombs: complex liquid crystal alumina composite mesostructures.. ACS Nano, 8(5), 4500-4509.
- SAXS characterization of polymer-embedded hollow nanoparticles and of their shell porosity. Journal of Applied Crystallography, 46(6), 1654-1664.
- A self-organized anisotropic liquid-crystal plasmonic metamaterial. Advanced Materials, 25(14), 1999-2004.
- Transformation from kinetically into thermodynamically controlled self-organization of complex helical columns with 3D periodicity assembled from dendronized perylene bisimides.. J Am Chem Soc, 135(10), 4129-4148.
- Liquid crystal plasmonic metamaterials. Proceedings of SPIE - The International Society for Optical Engineering, 8642.
- Modeling of the shape of polyethylene oxide single crystals and determination of the kinetic crystallization parameters: Theoretical and experimental approaches. Crystallography Reports, 57(6), 860-868.
- Characterizing size and porosity of hollow nanoparticles: SAXS, SANS, TEM, DLS, and adsorption isotherms compared.. Langmuir, 28(43), 15350-15361.
- Arrays of giant octagonal and square cylinders by liquid crystalline self-assembly of X-shaped polyphilic molecules.. Nat Commun, 3, 1104.
- One-Step Synthesis and Self-Assembly of Metal Oxide Nanoparticles into 3D Superlattices. ACS NANO, 6(5), 4382-4391.
- Optical properties of mesogen-coated gold nanoparticles. Proceedings of SPIE - The International Society for Optical Engineering, 8271.
- Control of anisotropic self-assembly of gold nanoparticles coated with mesogens. Journal of Materials Chemistry, 22(22), 11101-11106.
- Crystallization of poly(ethylene oxide) embedded with surface-modified SiO
nanoparticles. Polymer International.
- Self-organization of bent rod molecules into hexagonally ordered vesicular columns. Journal of the American Chemical Society, 134(33), 13871-13880.
- Complex tiling patterns in liquid crystals. Interface Focus, 2(5), 669-680.
- Nanoporous ordered materials: Osmotically shocked. Nature Materials, 11(1), 16-17.
- Nobel Prize for quasicrystals. Liquid Crystals Today, 21(1), 25-26.
- Two- and Three-Dimensional Liquid-Crystal Phases from Axial Bundles of Rodlike Polyphiles: Segmented Cylinders, Crossed Columns, and Ribbons between Sheets. Angewandte Chemie, 123(45), 10787-10790.
- Self-repairing complex helical columns generated via kinetically controlled self-assembly of dendronized perylene bisimides.. J Am Chem Soc, 133(45), 18479-18494.
- Two- and three-dimensional liquid-crystal phases from axial bundles of rodlike polyphiles: segmented cylinders, crossed columns, and ribbons between sheets.. Angew Chem Int Ed Engl, 50(45), 10599-10602.
- Self-Assembly at Different Length Scales: Polyphilic Star-Branched Liquid Crystals and Miktoarm Star Copolymers. ADV FUNCT MATER, 21(7), 1296-1323.
- Axial-Bundle Phases - New Modes of 2D, 3D, and Helical Columnar Self-Assembly in Liquid Crystalline Phases of Bolaamphiphiles with Swallow Tail Lateral Chains. J AM CHEM SOC, 133(13), 4906-4916.
- Complex multicolor tilings and critical phenomena in tetraphilic liquid crystals.. Science, 331(6022), 1302-1306.
- Liquid quasicrystals. Israel Journal of Chemistry, 51(11-12), 1206-1215.
- Electro-functional octupolar π-conjugated columnar liquid crystals. Journal of the American Chemical Society, 133(34), 13437-13444.
- Self-assembly of dendronized perylene bisimides into complex helical columns. Journal of the American Chemical Society, 133(31), 12197-12219.
- Influence of flexible spacers on liquid-crystalline self-assembly of T-shaped bolaamphiphiles. Journal of the American Chemical Society, 133(20), 7872-7881.
- Phospholipids with a stimuli-responsive thermotropic liquid-crystalline moiety. CHEM COMMUN, 47(24), 6885-6887.
- Deconstruction as a Strategy for the Design of Libraries of Self-Assembling Dendrons. Angewandte Chemie, 122(39), 7156-7159.
- Peculiarities of the crystal structure of modified banana-shaped mesogen. CRYSTALLOGR REP+, 55(5), 840-844.
- Self-assembly of hybrid dendrons into doubly segregated supramolecular polyhedral columns and vesicles.. J Am Chem Soc, 132(32), 11288-11305.
- Planar Alignment of Columnar Discotic Liquid Crystals by Isotropic Phase Dewetting on Chemically Patterned Surfaces. ADV FUNCT MATER, 20(6), 914-920.
- Structural and thermal study of mesomorphic dodecylammonium carrageenates.. J Colloid Interface Sci, 341(1), 117-123. View this article in WRRO
- GISAXS in the study of supramolecular and hybrid liquid crystals. Journal of Physics: Conference Series, 247.
- Body-centered cubic phase in 3-arm star mesogens: a torsional tapping AFM and GISAXS study. SOFT MATTER, 6(21), 5390-5396.
- Deconstruction as a strategy for the design of libraries of self-assembling dendrons. Angewandte Chemie - International Edition, 49(39), 7002-7005.
- Structure and pyroelectric behaviour of a twin-tapered bent core mesogen. Molecular Crystals and Liquid Crystals, 525, 212-218.
- Predicting the Structure of Supramolecular Dendrimers via the Analysis of Libraries of AB(3) and Constitutional Isomeric AB(2) Biphenylpropyl Ether Self-Assembling Dendrons. J AM CHEM SOC, 131(47), 17500-17521.
- Understanding Self-poisoning Phenomenon in Crystal Growth of Short-Chain Polymers. J PHYS CHEM B, 113(41), 13485-13490.
- Hollow Six-Stranded Helical Columns of a Helicene. Angewandte Chemie, 121(42), 7977-7980.
- Structure of liquid crystalline aerosol-OT and its alkylammonium salts.. Langmuir, 25(18), 11067-11072.
- Ordered Gold Nanoarrays: 3D Ordered Gold Strings by Coating Nanoparticles with Mesogens (Adv. Mater. 17/2009). Advanced Materials, 21(17), NA-NA.
- 3D Ordered Gold Strings by Coating Nanoparticles with Mesogens. ADV MATER, 21(17), 1746-+.
- Hollow six-stranded helical columns of a helicene.. Angew Chem Int Ed Engl, 48(42), 7837-7840.
- Siloxanes and carbosilanes as new building blocks for T-shaped bolaamphiphilic LC molecules. SOFT MATTER, 5(6), 1214-1227.
- Elucidating the Structure of the Pm(3)over-barn Cubic Phase of Supramolecular Dendrimers through the Modification of their Aliphatic to Aromatic Volume Ratio. CHEM-EUR J, 15(36), 8994-9004.
- 2D and 3D Ordered Columnar Liquid Crystal Phases by Bundles of Bolaamphiphiles with Swallow-Tail Side Chains. J AM CHEM SOC, 130(45), 14922-+.
- Liquid-Crystalline Kagome. Angewandte Chemie, 120(47), 9203-9206.
- Crystallography of 2D and 3D structures in liquid crystal amphiphiles and nanocomposites. Acta Crystallographica Section A Foundations of Crystallography, 64(a1), C31-C32.
- The trapezoidal cylinder phase: a new mode of self-assembly in liquid-crystalline soft matter.. J Am Chem Soc, 130(30), 9666-9667.
- Liquid-Crystal Engineering with Anchor-Shaped Molecules: Honeycombs with Hexagonal and Trigonal Symmetries Formed by Polyphilic Bent-Core Molecules. Angewandte Chemie, 120(32), 6169-6172.
- Inside Cover: Liquid-Crystal Engineering with Anchor-Shaped Molecules: Honeycombs with Hexagonal and Trigonal Symmetries Formed by Polyphilic Bent-Core Molecules (Angew. Chem. Int. Ed. 32/2008). Angewandte Chemie International Edition, 47(32), 5862-5862.
- Innentitelbild: Liquid-Crystal Engineering with Anchor-Shaped Molecules: Honeycombs with Hexagonal and Trigonal Symmetries Formed by Polyphilic Bent-Core Molecules (Angew. Chem. 32/2008). Angewandte Chemie, 120(32), 5946-5946.
- Polygonal cylinder phases of 3-alkyl-2,5-diphenylthiophene-based bolaamphiphiles: Changing symmetry by retaining net topology. CHEM MATER, 20(14), 4729-4738.
- Small angle X-ray and neutron scattering in the study of polymers and supramolecular systems. AIP Conference Proceedings, 989, 68.
- Testing the triple network structure of the cubic Im(3)over-bar-m (I) phase by isomorphous replacement and model refinement. J MATER CHEM, 18(25), 2953-2961.
- Liquid-crystal engineering with anchor-shaped molecules: Honeycombs with hexagonal and trigonal symmetries formed by polyphilic bent-core molecules. ANGEW CHEM INT EDIT, 47(32), 6080-6083.
- X-Shaped polyphilics: liquid crystal honeycombs with single-molecule walls. CHEM COMMUN(33), 3861-3863.
- Liquid-Crystalline Kagome. ANGEW CHEM INT EDIT, 47(47), 9063-9066.
- The Giant-Hexagon Cylinder Network—A Liquid-Crystalline Organization Formed by a T-Shaped Quaternary Amphiphile. Angewandte Chemie, 119(42), 8118-8121.
- Complex Liquid-Crystalline Superstructure of a π-Conjugated Oligothiophene. Angewandte Chemie, 119(41), 8002-8005.
- Isothermal crystallization kinetics and spherulitic morphology of poly(4-hydroxybutyric acid-alt-glycolic acid). J POLYM SCI POL PHYS, 45(18), 2640-2653.
- The triangular cylinder phase: a new mode of self-assembly in liquid-crystalline soft matter.. J Am Chem Soc, 129(31), 9578-9579.
- Semicrystalline and superlattice structures in an asymmetrically methyl-branched long-chain alkane. MACROMOLECULES, 40(16), 5750-5758.
- Effect of crystallization conditions on the shape of polymer single crystals: Experimental and theoretical approaches. CRYSTALLOGR REP+, 52(4), 707-720.
- Analysis of crystal habits bounded by asymmetrically curved faces: Polyethylene oligomers and poly(vinylidene fluoride). POLYMER, 48(7), 2087-2097.
- Asymmetric curvature of growth faces of polymer crystals. MACROMOLECULES, 40(3), 402-405.
- Complex liquid-crystalline superstructure of a pi-conjugated oligothiophene. ANGEW CHEM INT EDIT, 46(41), 7856-7859.
- The Giant-Hexagon cylinder network - A liquid-crystalline organization formed by a T-shaped quaternary amphiphile. ANGEW CHEM INT EDIT, 46(42), 7972-7975.
- Special issue honouring Professor David Bassett on the occasion of his retirement. POLYMER, 47(15), 5431-5432.
- Solution of the growth equation for asymmetric crystal faces. POLYMER, 47(15), 5505-5512.
- Strain-induced mesophase and hard-elastic behaviour of biodegradable polyhydroxyalkanoates fibers. POLYMER, 47(15), 5678-5690.
- Self-assembly in action. SCIENCE, 313(5783), 55-56.
- Inflation rules of square-triangle tilings: from approximants to dodecagonal liquid quasicrystals. PHILOS MAG, 86(6-8), 1093-1103.
- Carbohydrate rod conjugates: Ternary rod-coil molecules forming complex liquid crystal structures. J AM CHEM SOC, 127(47), 16578-16591.
- Real-time neutron scattering study of transient phases in polymer crystallization. MACROMOLECULES, 38(17), 7201-7204.
- Frank-Kasper, quasicrystalline and related phases in liquid crystals. SOFT MATTER, 1(2), 95-106.
- A triple-network tricontinuous cubic liquid crystal.. Nat Mater, 4(7), 562-567.
- AFM study of lamellar structure of melt-crystallized n-alkane C390H782. MACROMOLECULES, 38(12), 4962-4965.
- Organisation in two series of low-dimensional polymer electrolytes with high ambient lithium salt conductivity.. Faraday Discuss, 128, 363-378.
- The effect of self-poisoning on crystal morphology and growth rates. ADV POLYM SCI, 180, 45-87.
- Structure and inter-phase stability in solvent-free low-dimensional polymer electrolytes with high lithium conductivity.. Dalton Trans(19), 3053-3060.
- Liquid Crystals with Complex Superstructures. Angewandte Chemie, 116(35), 4721-4725.
- A new type of square columnar liquid crystalline phases formed by facial amphiphilic triblock molecules. J AM CHEM SOC, 126(28), 8608-8609.
- Designing libraries of first generation AB(3) and AB(2) self-assembling dendrons via the primary structure generated from combinations of (AB)(y)-AB(3) and (AB)(y)-AB(2) building blocks. J AM CHEM SOC, 126(19), 6078-6094.
- Supramolecular dendritic liquid quasicrystals.. Nature, 428(6979), 157-160. View this article in WRRO
- Infrared active methyl group vibrations in tetratetracontane: A probe for chain end organization and crystal structure. J PHYS CHEM B, 108(10), 3130-3139.
- Solvent-free low-dimensional polymer electrolytes for lithium-polymer batteries.. Chem Rec, 4(3), 176-191.
- Liquid crystals with complex superstructures. ANGEW CHEM INT EDIT, 43(35), 4621-4625.
- Application of isomorphous replacement in the structure determination of a cubic liquid crystal phase and location of counterions.. J Am Chem Soc, 125(51), 15974-15980.
- Chain unfolding in single crystals of ultralong alkane C390H782 and polyethylene: An atomic force microscopy study. MACROMOLECULES, 36(15), 5637-5649.
- In situ solution crystallization study of n-C246H494: Self-poisoning and morphology of polymethylene crystals. MACROMOLECULES, 36(14), 5214-5225.
- Triple-layer superlattice in deuterium-labeled binary ultralong alkanes: A study by small-angle neutron and X-ray scattering. MACROMOLECULES, 36(13), 4686-4688.
- Thick lamellar textures and high ambient conductivity in de-blended mixtures of low-dimensional systems of two polymers and Li salts. ELECTROCHIMICA ACTA, 48(14-16), 1939-1951.
- Step initiation and propagation rate minima in solution crystallization of five long alkanes. MACROMOLECULES, 36(11), 3812-3814.
- Crystal-amorphous polymer interface studied by neutron and x-ray scattering on labeled binary ultralong alkanes.. Phys Rev Lett, 90(15), 155508.
- Giant supramolecular liquid crystal lattice.. Science, 299(5610), 1208-1211.
- Interrelationships of nanometer and subnanometer structures in a polynorbornene containing second generation liquid-crystalline monodendrons as side groups. MACROMOLECULES, 35(25), 9426-9433.
- Chain tilt and surface disorder in lamellar crystals. A FTIR and SAXS study of labeled long alkanes. MACROMOLECULES, 35(20), 7730-7741.
- Phase behaviors and molecular and supramolecular structural identifications of a liquid crystalline second generation monodendron. CHEM MATER, 14(5), 2384-2392.
- Polymer compatibility, phase separation and high ambient conductivity in low - Dimensional polymer electrolyte blends with lithium salts. Ionics, 8(3-4), 201-209.
- Learning polymer crystallization with the aid of linear, branched and cyclic model compounds.. Chem Rev, 101(12), 4157-4188.
- Semicrystalline lamellar phase in binary mixtures of very long chain n-alkanes. MACROMOLECULES, 34(20), 6945-6954.
- Asymmetric curvature of {110} crystal growth faces in polyethylene oligomers. MACROMOLECULES, 34(15), 5180-5185.
- Novel layered superstructures in mixed ultralong n-alkanes.. Phys Rev Lett, 86(21), 4875-4878.
- Synthesis and structural analysis of two constitutional isomeric libraries of AB(2)-based monodendrons and supramolecular dendrimers. J AM CHEM SOC, 123(7), 1302-1315.
- Poly(oxazoline)s with tapered minidendritic side groups as models for the design of synthetic macromolecules with tertiary structure. A demonstration of the limitations of living polymerization in the design of 3-D structures based on single polymer chains. BIOMACROMOLECULES, 2(3), 729-740.
- Dilution wave and negative-order crystallization kinetics of chain molecules.. Phys Rev Lett, 85(20), 4397-4400.
- Increasing the diameter of cylindrical and spherical supramolecular dendrimers by decreasing the solid angle of their monodendrons via periphery functionalization. J AM CHEM SOC, 122(42), 10273-10281.
- Phase identification in a series of liquid crystalline TPP polyethers and copolyethers having highly ordered mesophase structures. 8. Phase and structural evolution in a series of copolyethers containing odd-numbered methylene units in both comonomers. MACROMOLECULES, 33(14), 5159-5168.
- Von molekularen Kreissegmenten, Scheiben und Kegeln zu supramolekularen Zylindern und Kugeln mit an der Peripherie modifizierten Fréchet-Monodendren. Angewandte Chemie, 112(9), 1661-1666.
- Heat-shrinking spherical and columnar supramolecular dendrimers: their interconversion and dependence of their shape on molecular taper angle. Chemistry, 6(7), 1258-1266.
- Molecular Recognition Directed Self-Assembly of Supramolecular Liquid Crystals. Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals, 254(1), 137-196.
- Molecular-Recognition-Directed Self-Assembly of Supramolecular Polymers. Journal of Macromolecular Science, Part A, 31(8), 1031-1070.
- Molecular-Recognition-Directed Self-Assembly of Supramolecular Polymers. Journal of Macromolecular Science, Part A, 31(8), 1031-1070.
- Structure and conductivity of liquid crystal channel-like linic complexes of taper-shaped compounds. Advanced Materials for Optics and Electronics, 4(4), 303-313.
- General discussion. Faraday Discussions, 95, 145-172.
h ) in a non-discotic copolyether and the novel 2-dimensional to 3-dimensional φh -SB transition. American Chemical Society, Polymer Preprints, Division of Polymer Chemistry, 32(1), 282-283.
Liquid crystalline polyethers based on conformational isomerism. 16. hexagonal columnar phase (φ- Simultaneous X-Ray/DSC Study of Mesomorphism in Polymers with a Semiflexible Mesogen. Macromolecules, 23(14), 3411-3416.
- Orientability of Rigid Rodlike Molecules in Solution and Controlled Preparation of Model Systems. MRS Proceedings, 134.
- Radiation effects in polyethylene and n-alkanes. Journal of Materials Science, 16(10), 2635-2656.
- Molecular Simulations of Quantized Lamellar Thickening in Polyethylenes with Regularly Spaced Brominated Groups. Macromolecules.
- Facile Construction of Soft Plasmonic Sensors with Exceptional Optical Activity for Quantitative Chiral Detection. Small.
- Plasmonic Sensors with Exceptional Optical Activity for Quantitative Chiral Detection. Small.
- Thermotropic “Plumber’s Nightmare” ‐ A Tight Liquid Organic Double Framework. Angewandte Chemie International Edition.
- Thermotropic “Plumber’s Nightmare” ‐ A Tight Liquid Organic Double Framework. Angewandte Chemie.
- Orientational transitions of discotic columnar liquid crystals in cylindrical pores. Soft Matter.
- Supertwisted Chiral Gyroid Mesophase in Chiral Rod‐like Compounds. Angewandte Chemie International Edition.
- Supertwisted Chiral Gyroid Mesophase in Chiral Rod‐like Compounds. Angewandte Chemie.
- Continuous Spectrum of Morphologies and Phase Behavior across the Contact Zone from Poly(
l -lactide) to Poly(d -lactide): Stereocomplex, Homocrystal, and Between. Macromolecules. - Enantiomers Self-Sort into Separate Counter-Twisted Ribbons of the Fddd Liquid Crystal─Antiferrochirality and Parachirality. Journal of the American Chemical Society.
- 3D Morphology of Different Crystal Forms in β-Nucleated and Fiber-Sheared Polypropylene: α-Teardrops, α-Teeth, and β-Fans. Macromolecules.
- Crystalline Order Propagates Across Thick Layers of Water in Solutions of Supramolecular Nanotubes. Chemistry – A European Journal.
- A columnar liquid quasicrystal with a honeycomb structure that consists of triangular, square and trapezoidal cells. Nature Chemistry.
- The Effect of Mesogenic Coronas on the Type and Anisotropy of Gold Nanoparticle Superlattices: When Can the Tail Wag the Dog?. Chemistry – A European Journal.
- Poisoning by Purity: What Stops Stereocomplex Crystallization in Polylactide Racemate?. Macromolecules.
- Reentrant 2D Nanostructured Liquid Crystals by Competition between Molecular Packing and Conformation: Potential Design for Multistep Switching of Ionic Conductivity. ChemPhysChem.
- Multicompartment Nanoparticles by Crystallization‐Driven Self‐Assembly of Star Polymers: Combining High Stability and Loading Capacity. Macromolecular Rapid Communications, 2200706-2200706.
- Morphology of Shear-Induced Polymer Cylindrites Revealed by 3D Optical Imaging. Macromolecules.
- Self‐assembly of gold nanoparticles into an adjustable plasmonic 3D lattice using Janus‐type forked mesogenic ligands. Chemistry – An Asian Journal.
- Gradient H‐Bonding Binder Enables Stable High‐Areal‐Capacity Si‐Based Anodes in Pouch Cells. Advanced Materials, 2104416-2104416.
- Asymmetric Incorporation of Silver Nanoparticles in Polymeric Assemblies by Coassembly of Tadpole‐Like Nanoparticles and Amphiphilic Block Copolymers. Macromolecular Rapid Communications, 2100354-2100354.
- Roughening Transition and Quasi-continuous Melting of Monolayers of Ultra-long Alkanes: Why Bulk Polymer Melting Is Strongly First-Order. Macromolecules.
- Spontaneously chiral cubic liquid crystal: three interpenetrating networks with a twist. Journal of Materials Chemistry C, 8(16), 5389-5398.
- Switching of ionic conductivities in columnar liquid-crystalline anilinium salts: effects of alkyl chains, ammonium cations and counter anions on thermal properties and switching temperatures. Molecular Systems Design & Engineering, 4(2), 342-347.
- β-Ga2O3 nanorod arrays with high light-to-electron conversion for solar-blind deep ultraviolet photodetection. RSC Advances, 9(11), 6064-6069.
- Mesomorphism of a new series of catanionic 4-(1-pentylheptyl)benzenesulfonates. Soft Matter, 10(39), 7887-7896.
- ChemInform Abstract: Learning Polymer Crystallization with the Aid of Linear, Branched and Cyclic Model Compounds. ChemInform, 33(15), no-no.
- ChemInform Abstract: Novel Synthesis of Calamitic and Discotic Liquid Crystalline Derivatives of Tetrathiafulvalene (TTF).. ChemInform, 29(18), no-no.
- ChemInform Abstract: Molecular Recognition Directed Self-Assembly of Supramolecular Architectures. ChemInform, 26(13), no-no.
- ChemInform Abstract: Self-Assembly of Taper-Shaped Monoesters of Oligo(ethylene Oxide) with 3,4,5-Tris(n-dodecan-1-yloxy)benzoic Acid and of Their Polymethacrylates into Tubular Supramolecular Architectures Displaying a Columnar Hexagonal Mesophase.. ChemInform, 25(15), no-no.
- ChemInform Abstract: Poly(2-vinyloxyethyl-3,4,5-tris(4-(n-dodecanyloxy)benzyloxy)benzoate): A Self-Assembled Supramolecular Polymer Similar to Tobacco Mosaic Virus.. ChemInform, 24(15), no-no.
- Macroscopic chirality of twist-bend nematic phase in bent dimers confirmed by circular dichroism. Journal of Materials Chemistry C, 8(3), 1041-1047.
Chapters
- X-ray scattering, Series in Soft Condensed Matter (pp. 209-253). WORLD SCIENTIFIC
- Crystallization of Uniform Oligomers, Encyclopedia of Materials: Science and Technology (pp. 1-6). Elsevier
- “Liquid Crystallization” Mechanism of Liquid Crystalline Polymers, Ordering in Macromolecular Systems (pp. 89-97). Springer Berlin Heidelberg
- What Do Long Alkanes Reveal About Polymers?, Integration of Fundamental Polymer Science and Technology—2 (pp. 346-362). Springer Netherlands
- Side-Branched Polyphiles and Polygonal Cylinder Phases (pp. 1-46). Wiley-VCH Verlag GmbH & Co. KGaA
- Cubic and Other 3D Thermotropic Liquid Crystal Phases and Quasicrystals (pp. 1-74). Wiley-VCH Verlag GmbH & Co. KGaA
- The role of transient hexagonal phase in crystallization of polymers, Solidification Processes in Polymers (pp. 42-45). Steinkopff
- Hexagonal columnar phases in polymers, Solidification Processes in Polymers (pp. 52-56). Steinkopff
Conference proceedings papers
- Low dimensional polymer electrolytes with enhanced Li+ conductivities. JOURNAL OF POWER SOURCES, Vol. 146(1-2) (pp 418-422)
- High lithium conductivities in weakly-ionophilic low-dimensional block copolymer electrolytes. ELECTROCHIMICA ACTA, Vol. 50(19) (pp 3815-3826)
- On perpendicular and tilted chains in lamellar crystals. JOURNAL OF MACROMOLECULAR SCIENCE-PHYSICS, Vol. B42(3-4) (pp 915-927)
- Columnar phase in main chain and comb-like polymers. MOLECULAR CRYSTALS AND LIQUID CRYSTALS, Vol. 396 (pp 155-168)
- Semicrystalline and superlattice structures in binary mixture of long chain n-alkanes C194H390 and C294H590. JOURNAL OF MACROMOLECULAR SCIENCE-PHYSICS, Vol. B41(4-6) (pp 1305-1320)
- Crystallization rate minima in ultra-longn-alkanes. Acta Crystallographica Section A Foundations of Crystallography, Vol. 52(a1) (pp C508-C508)
Preprints
- Molecular Simulations of Quantized Lamellar Thickening in Polyethylenes with Regularly Spaced Brominated Groups, arXiv.
- A Columnar Liquid Quasicrystal – Honeycomb with Triangular, Square and Trapezoidal Cells, Research Square.
- Molecular organization in the twist-bend nematic phase by resonant X-ray scattering at the Se K-edge and by SAXS, WAXS and GIXRD, arXiv.
- Bowls, Vases and Goblets – The Microcrockery of Polymer and Nanocomposite Morphology Revealed by Two-Photon Optical Tomography, Research Square Platform LLC.
- Liquid crystal phase of counter-rotating staircases – A case of antiferrochirality, Research Square Platform LLC.
- X-ray diffraction on smectic liquid crystals: Determining molecular arrangement from diffraction intensities. Journal of Molecular Liquids, 126866-126866.
- Professional activities and memberships
-
- IUPAC 2017 Distinguished Award for Novel Materials and their Synthesis
- Invited speaker at over 80 international conferences
- Visiting Professor at Universities of Hiroshima, Barcelona, Zhejiang Sci-Tech and Seoul National University
- On Editorial Board of Polymer Journal
- Member of the Committee of the British Liquid Crystal Society
- Member of the Beam Allocation Panel of the UK Synchrotron Radiation Source
- Member of the EPSRC College
- Over 10,000 citations, h-index51